Myles Benton Herbert

Title: The Innovative Work of Myles Benton Herbert in Olefin Metathesis Catalysts

Introduction

Myles Benton Herbert is an accomplished inventor based in Pasadena, California. With a remarkable portfolio that includes three patents, Herbert has made significant strides in the field of olefin metathesis, particularly with Z-selective catalysts that are poised to enhance efficiency in chemical synthesis.

Latest Patents

Herbert's latest patents focus on Z-selective olefin metathesis catalysts and their synthetic procedures. These inventions detail new C—H activated olefin metathesis catalyst compounds that are beneficial for the metathesis of olefins and olefin compounds. His work emphasizes the preparation and use of these advanced catalysts, which typically comprise a Group 8 metal, an alkylidene moiety, an anionic ligand, and neutral ligands. These catalysts demonstrate remarkable effectiveness in catalysis, organic synthesis, polymer chemistry, and the production of both industrial and fine chemicals.

One such innovation is a novel chelated ruthenium-based metathesis catalyst featuring an N-2,6-diisopropylphenyl group. This catalyst showcases exceptional selectivity for Z-olefins (over 95%) and delivers outstanding turnover numbers (TONs) of up to 7,400 across various homodimerization and metathesis reactions. Herbert's development includes the synthesis of these catalysts through an improved method utilizing sodium carboxylates, allowing for enhanced salt metathesis and C—H activation.

Career Highlights

Herbert is associated with the California Institute of Technology, a premier institution renowned for its impactful contributions to science and technology. His role at Caltech allows him to collaborate with leading minds in chemistry, enriching the research environment with his innovative ideas.

Collaborations

Throughout his career, Myles Benton Herbert has collaborated with notable peers, including esteemed chemists Robert H. Grubbs and Benjamin Keith Keitz. These partnerships have fostered a stimulating exchange of ideas and propelled advancements in the realm of metathesis catalysis.

Conclusion

Myles Benton Herbert's contributions to the development of Z-selective olefin metathesis catalysts highlight his status as an influential inventor in the field of chemistry. His innovative work not only advances scientific understanding but also holds the potential for substantial industrial applications in catalysis and organic synthesis. Herbert's ongoing endeavors promise to continue reshaping the landscape of chemical innovation.