The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 14, 2020

Filed:

Feb. 28, 2017
Applicant:

Tokyo Electron Limited, Tokyo, JP;

Inventors:

Michael A. Carcasi, Austin, TX (US);

Joshua S. Hooge, Austin, TX (US);

Benjamen M. Rathsack, Austin, TX (US);

Seiji Nagahara, Sagamihara, JP;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
G03F 7/038 (2006.01); G03F 7/039 (2006.01); G03F 7/20 (2006.01); G03F 7/09 (2006.01); G03F 7/30 (2006.01); G03F 7/26 (2006.01); G03F 7/38 (2006.01); G03F 7/11 (2006.01); H01L 21/027 (2006.01); G03F 7/004 (2006.01);
U.S. Cl.
CPC ...
G03F 7/2022 (2013.01); G03F 7/0045 (2013.01); G03F 7/0382 (2013.01); G03F 7/0392 (2013.01); G03F 7/09 (2013.01); G03F 7/091 (2013.01); G03F 7/11 (2013.01); G03F 7/2002 (2013.01); G03F 7/2004 (2013.01); G03F 7/2024 (2013.01); G03F 7/26 (2013.01); G03F 7/30 (2013.01); G03F 7/38 (2013.01); H01L 21/0271 (2013.01); H01L 21/0274 (2013.01); H01L 21/0276 (2013.01);
Abstract

The disclosure herein describes methods for Photosensitized Chemically Amplified Resist Chemicals (PS-CAR) to pattern light sensitive films on a semiconductor substrate. In one embodiment, a two-step exposure process may generate higher acid concentration regions within a photoresist layer. The PS-CAR chemicals may include photoacid generators (PAGs) and photosensitizer elements that enhance the decomposition of the PAGs into acid. The first exposure may be a patterned EUV exposure that generates an initial amount of acid and photosensitizer. The second exposure may be a non-EUV flood exposure that excites the photosensitizer which increases the acid generation rate where the photosensitizer is located on the substrate. The distribution of energy during the exposures may be optimized by using certain characteristics (e.g., thickness, index of refraction, doping) of the photoresist layer, an underlying layer, and/or an overlying layer.


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