The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 31, 2017

Filed:

Jun. 24, 2013
Applicants:

Dow Global Technologies Llc, Midland, MI (US);

Rohm and Haas Electronic Materials Llc, Marlborough, MA (US);

Inventors:

Peter Trefonas, III, Medway, MA (US);

Deyan Wang, Hudson, MA (US);

Rahul Sharma, Pearland, TX (US);

Phillip D. Hustad, Watertown, MA (US);

Mingqi Li, Shrewsbury, MA (US);

Assignees:

DOW GLOBAL TECHNOLOGIES LLC, Midland, MI (US);

ROHM AND HAAS ELECTRONIC MATERIALS LLC, Marlborough, MA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08L 53/00 (2006.01); C08L 63/00 (2006.01); B32B 43/00 (2006.01); B05D 7/00 (2006.01); B05D 1/18 (2006.01); G03F 7/00 (2006.01); B32B 27/08 (2006.01);
U.S. Cl.
CPC ...
B32B 43/00 (2013.01); B05D 1/185 (2013.01); B05D 7/52 (2013.01); B32B 27/08 (2013.01); C08L 53/00 (2013.01); G03F 7/0002 (2013.01); B32B 2457/14 (2013.01); C08F 2438/03 (2013.01); Y10T 428/24942 (2015.01);
Abstract

Disclosed herein is a method comprising disposing a first composition comprising a first block copolymer upon a substrate; where the first block copolymer comprises a first segment and a second segment that are covalently bonded to each other and that are chemically different from each other; where the first segment has a first surface free energy and where the second segment has a second surface free energy; and disposing a second composition comprising an second copolymer upon a free surface of the first block copolymer; where the second copolymer comprises a surface free energy reducing moiety; where the surface free energy reducing moiety has a lower surface free energy than the first surface free energy and the second surface free energy; the second copolymer further comprising one or more moieties having an affinity to the first block copolymer; where the surface free energy reducing moiety is chemically different from the first segment and from the second segment.


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