The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 17, 2020

Filed:

May. 22, 2018
Applicant:

University of Kansas, Lawrence, KS (US);

Inventors:

Judy Z. Wu, Lawrence, KS (US);

Jamie Wilt, Olathe, KS (US);

Ryan Goul, Topeka, KS (US);

Jagaran Acharya, Lawrence, KS (US);

Assignee:

UNIVERSITY OF KANSAS, Lawrence, KS (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01L 43/12 (2006.01); H01L 43/08 (2006.01); H01L 39/22 (2006.01); H01L 39/24 (2006.01);
U.S. Cl.
CPC ...
H01L 43/12 (2013.01); H01L 39/223 (2013.01); H01L 39/2493 (2013.01); H01L 43/08 (2013.01);
Abstract

Methods for forming tunnel barrier layers are provided, including a method comprising exposing a surface of a material, the surface free of oxygen, to an initial water pulse for a pulse time and at a pulse temperature, the pulse time and pulse temperature selected to maximize hydroxylation of the surface; and exposing the hydroxylated surface to alternating, separated pulses of precursors under conditions to induce reactions between the hydroxylated surface and the precursors to form a tunnel barrier layer on the surface of the material via atomic layer deposition (ALD), the tunnel barrier layer having an average thickness of no more than 1 nm and being formed without an intervening interfacial layer between the tunnel barrier layer and the surface of the material.


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