The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 06, 2017

Filed:

Sep. 30, 2016
Applicants:

International Business Machines Corporation, Armonk, NY (US);

Shin-etsu Chemical Co., Ltd., Tokyo, JP;

Inventors:

Martin Glodde, Pine Brook, NJ (US);

Ratnam Sooriyakumaran, San Jose, CA (US);

Seiichiro Tachibana, Tokyo, JP;

Hoa D. Truong, Los Altos, CA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
G03F 7/11 (2006.01); G03F 7/09 (2006.01); C09D 125/18 (2006.01); C09D 133/14 (2006.01); G03F 7/20 (2006.01); G03F 7/16 (2006.01); H01L 21/308 (2006.01);
U.S. Cl.
CPC ...
G03F 7/094 (2013.01); C09D 125/18 (2013.01); C09D 133/14 (2013.01); G03F 7/162 (2013.01); G03F 7/168 (2013.01); G03F 7/2004 (2013.01); G03F 7/2006 (2013.01); G03F 7/2008 (2013.01); G03F 7/2016 (2013.01); H01L 21/3081 (2013.01); H01L 21/3083 (2013.01);
Abstract

A layered structure includes a substrate; an underlayer including a reversibly crosslinked polymer and/or oligomer interconnected by ester functionalities; a silicon-containing mask overlaying the underlayer; and a photoresist overlaying the silicon-containing hardmask layer. Also described are multilayer lithographic processes and processes of forming the underlayer, which generally includes coating an underlayer composition onto a surface of the substrate at a thickness effective to provide a planar upper surface, wherein the underlayer composition includes a polymer including terminal alcohol groups, a multifunctional anhydride, and a solvent. The underlayer composition is heated to a temperature to effect a crosslinking reaction between the multifunctional anhydride and the terminal alcohol groups to form the ester functionalities, which can be selectively removed (reversibly crosslinked) using a wet etchant.


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