The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 16, 2017

Filed:

Dec. 19, 2014
Applicants:

W. L. Gore & Associates, Inc., Newark, DE (US);

W. L. Gore & Associates Gmbh, Putzbrunn, DE;

Inventors:

Lawrence A. Ford, München, DE;

Michael E. Kennedy, Oxford, PA (US);

Shaofeng Ran, Kennett Square, PA (US);

Todd S. Sayler, Bear, DE (US);

Gregory J. Shafer, Oxford, PA (US);

Assignees:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 259/08 (2006.01); C08F 214/26 (2006.01); B32B 27/06 (2006.01); B32B 27/32 (2006.01); C08J 5/18 (2006.01); A61L 27/16 (2006.01); A61L 27/50 (2006.01); A61L 27/56 (2006.01); A61L 31/04 (2006.01); A61L 31/14 (2006.01); B29C 55/00 (2006.01); C08J 9/00 (2006.01); B29C 44/56 (2006.01); A61L 27/26 (2006.01); A61L 27/34 (2006.01); A61L 29/04 (2006.01); A61L 29/08 (2006.01); A61L 31/10 (2006.01); B29K 27/12 (2006.01); B29K 27/00 (2006.01); B29K 27/18 (2006.01); B29K 105/04 (2006.01);
U.S. Cl.
CPC ...
C08J 5/18 (2013.01); A61L 27/16 (2013.01); A61L 27/26 (2013.01); A61L 27/34 (2013.01); A61L 27/507 (2013.01); A61L 27/56 (2013.01); A61L 29/041 (2013.01); A61L 29/049 (2013.01); A61L 29/085 (2013.01); A61L 31/041 (2013.01); A61L 31/048 (2013.01); A61L 31/10 (2013.01); A61L 31/146 (2013.01); B29C 44/5627 (2013.01); B29C 55/005 (2013.01); B32B 27/06 (2013.01); B32B 27/322 (2013.01); C08F 259/08 (2013.01); C08J 9/00 (2013.01); B29K 2027/00 (2013.01); B29K 2027/12 (2013.01); B29K 2027/18 (2013.01); B29K 2105/04 (2013.01); B32B 2250/00 (2013.01); B32B 2250/24 (2013.01); B32B 2307/72 (2013.01); B32B 2327/18 (2013.01); B32B 2437/00 (2013.01); B32B 2439/00 (2013.01); B32B 2535/00 (2013.01); B32B 2581/00 (2013.01); C08F 214/26 (2013.01); C08J 2207/02 (2013.01); C08J 2327/18 (2013.01); Y10T 428/1376 (2015.01); Y10T 428/28 (2015.01); Y10T 428/31544 (2015.04);
Abstract

A tetrafluoroethylene (TFE) copolymer film having a first endotherm between about 50° C. and about 300° C., a second endotherm between about 320° C. and about 350° C., and a third endotherm between about 350° C. and about 400° C. is provided. In exemplary embodiments, the third endotherm is approximately 380° C. In some embodiments, the second endotherm is between about 320° C. and about 330° C. or between about 330° C. and about 350° C. TFE copolymer films have a methane permeability less than about 20 μg*micron/cm/min. In addition, the dense articles have a void volume of less than about 20%. Methods for dense articles from core shell tetrafluoroethylene copolymers are also provided. The dense articles exhibit improved physical and mechanical properties such as adhesion and barrier properties.


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