The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 28, 2017

Filed:

Aug. 28, 2013
Applicant:

The United States of America, As Represented BY the Secretary of Commerce (Nist), Washington, DC (US);

Inventors:

Thomas P. Moffat, Gaithersburg, MD (US);

Yihua Liu, Gaithersburg, MD (US);

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C25D 3/50 (2006.01); C25D 5/18 (2006.01); C25D 5/34 (2006.01); C25D 5/36 (2006.01); C25D 5/38 (2006.01); C25D 5/40 (2006.01);
U.S. Cl.
CPC ...
C25D 3/50 (2013.01); C25D 5/18 (2013.01); C25D 5/34 (2013.01); C25D 5/36 (2013.01); C25D 5/38 (2013.01); C25D 5/40 (2013.01);
Abstract

A self-terminating rapid process for controlled growth of platinum or platinum alloy monolayer films from a KPtCl—NaCl—NaBr electrolyte. Using the present process, platinum deposition may be quenched at potentials just negative of proton reduction by an alteration of the double layer structure induced by a saturated surface coverage of underpotential deposited hydrogen. The surface may be reactivated for platinum deposition by stepping the potential to more positive values where underpotential deposited hydrogen is oxidized and fresh sites for absorption of platinum chloride become available. Periodic pulsing of the potential enables sequential deposition of two dimensional platinum layers to fabricate films of desired thickness relevant to a range of advanced technologies, from catalysis to magnetics and electronics.


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