The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 31, 2016

Filed:

Feb. 20, 2012
Applicants:

Joerg Sundermeyer, Marburg, DE;

Wolf Schorn, Giessen, DE;

Ralf Karch, Kleinostheim, DE;

Inventors:

Joerg Sundermeyer, Marburg, DE;

Wolf Schorn, Giessen, DE;

Ralf Karch, Kleinostheim, DE;

Assignee:

Umicore AG & Co. KG, Hamau-Wolfgang, DE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07F 15/04 (2006.01); C07F 15/00 (2006.01); C07F 7/00 (2006.01); C07F 5/00 (2006.01); B01J 31/18 (2006.01); C07C 257/12 (2006.01); C07C 257/14 (2006.01); C23C 16/30 (2006.01); C23C 16/34 (2006.01); C07F 5/06 (2006.01); C07F 7/12 (2006.01); C07F 7/28 (2006.01); C07F 7/10 (2006.01);
U.S. Cl.
CPC ...
C07F 15/04 (2013.01); B01J 31/1805 (2013.01); C07C 257/12 (2013.01); C07C 257/14 (2013.01); C07F 5/00 (2013.01); C07F 5/063 (2013.01); C07F 5/066 (2013.01); C07F 5/069 (2013.01); C07F 7/00 (2013.01); C07F 7/10 (2013.01); C07F 7/12 (2013.01); C07F 7/28 (2013.01); C07F 15/006 (2013.01); C23C 16/303 (2013.01); C23C 16/345 (2013.01); B01J 2231/321 (2013.01); B01J 2531/0238 (2013.01); B01J 2531/10 (2013.01); B01J 2531/30 (2013.01); B01J 2531/40 (2013.01); B01J 2531/50 (2013.01);
Abstract

The invention relates to new metal complexes having N-aminoamidinate ligands, more particularly metal complexes having N,N'-bis(dimethylamino)acetamidinate, N,N′-bis(dimethylamino)formamidinate, N-dimethylaminoacetamidinate or N-dimethylamino-N′-isopropyl-acetamidinate ligands as well as to their preparation and use. The metal complexes are characterized by a five-membered chelate ring. The metal complexes are formed with the metals from the main groups of the PTE, but also with transition-group elements such as tantalum (Ta), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu) or zinc (Zn), and also with precious metals such as palladium (Pd). The complexes of the invention find use as precursors for the preparation of functional layers by means of gas-phase thin-film processes such as CVD, MO-CVD and ALD. Additionally they may be used as catalysts for olefin hydroamination and for olefin polymerization.


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