The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 04, 2015

Filed:

Mar. 13, 2013
Applicant:

Wisconsin Alumni Research Fondation, Madison, WI (US);

Inventors:

Padma Gopalan, Madison, WI (US);

Daniel Patrick Sweat, Madison, WI (US);

Myungwoong Kim, Madison, WI (US);

Eungnak Han, Hillsboro, OR (US);

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
B05D 1/36 (2006.01); B05D 3/00 (2006.01); B05D 5/00 (2006.01); G03F 1/50 (2012.01); G03F 7/20 (2006.01);
U.S. Cl.
CPC ...
G03F 1/50 (2013.01); B05D 5/00 (2013.01); B05D 2506/00 (2013.01); G03F 7/20 (2013.01);
Abstract

Block copolymer-based mask structures for the growth of patterned polymer brushes via surface-initiated atom transfer radical polymerization (SI-ATRP) are provided. Also provided are methods of making the mask structures and methods of using the mask structures to grow patterned polymer brushes. The mask structures comprise a substrate having a surface, a neutral layer comprising a crosslinked copolymer film disposed on the surface of the substrate and a domain-forming block copolymer film disposed on the crosslinked copolymer film. The crosslinked copolymer film comprises crosslinked random copolymer chains having pendant alkyl halide functional groups that are capable of acting as ATRP initiating sites.


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