The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 24, 2015

Filed:

Jan. 17, 2014
Applicant:

3m Innovative Properties Company, St. Paul, MN (US);

Inventors:

Samantha D. Smith, Minneapolis, MN (US);

Gene H. Shipman, Cottage Grove, MN (US);

Robert M. Floyd, Coon Rapids, MN (US);

Harold Todd Freemyer, Woodbury, MN (US);

Steven J. Hamrock, Stillwater, MN (US);

Michael A. Yandrasits, Hastings, MN (US);

David G. S. Walton, Honolulu, HI (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 8/10 (2006.01); H01M 2/16 (2006.01); B05D 1/14 (2006.01); B32B 1/08 (2006.01); B01D 65/00 (2006.01); B01D 29/00 (2006.01); B01D 67/00 (2006.01); B01D 69/14 (2006.01); B01D 71/34 (2006.01); C08J 5/22 (2006.01);
U.S. Cl.
CPC ...
H01M 8/1044 (2013.01); B01D 67/0009 (2013.01); B01D 67/0011 (2013.01); B01D 67/0016 (2013.01); B01D 67/0027 (2013.01); B01D 69/141 (2013.01); B01D 71/34 (2013.01); C08J 5/2281 (2013.01); H01M 8/1023 (2013.01); H01M 8/1039 (2013.01); H01M 8/1048 (2013.01); H01M 8/106 (2013.01); H01M 8/1079 (2013.01); H01M 8/1083 (2013.01); Y02E 60/521 (2013.01); B01D 2323/46 (2013.01); B01D 2325/022 (2013.01); B01D 2325/20 (2013.01); B01D 2325/24 (2013.01); C08J 2327/16 (2013.01);
Abstract

Shaped microporous articles are produced from polyvinylidene fluoride (PVDF) and nucleating agents using thermally induced phase separation (TIPS) processes. The shaped microporous article is oriented in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0. The shaped article may also comprise a diluent, glyceryl triacetate. The shaped microporous article may also have the micropores filled with a sufficient quantity of ion conducting electrolyte to allow the membrane to function as an ion conductive membrane. The method of making a microporous article comprises the steps of melt blending polyvinylidene fluoride, nucleating agent and glyceryl triacetate; forming a shaped article of the mixture; cooling the shaped article to cause crystallization of the polyvinylidene fluoride and phase separation of the polyvinylidene fluoride and glyceryl triacetate; and stretching the shaped article in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0.


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