The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 06, 2015

Filed:

Aug. 11, 2010
Applicants:

Jason E. Hein, La Jolla, CA (US);

Jonathan C. Tripp, Westfield, NJ (US);

Larissa Krasnova, San Diego, CA (US);

K. Barry Sharpless, La Jolla, CA (US);

Valery V. Fokin, Oceanside, CA (US);

Inventors:

Jason E. Hein, La Jolla, CA (US);

Jonathan C. Tripp, Westfield, NJ (US);

Larissa Krasnova, San Diego, CA (US);

K. Barry Sharpless, La Jolla, CA (US);

Valery V. Fokin, Oceanside, CA (US);

Assignee:

The Scripps Research Institute, La Jolla, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 403/02 (2006.01); B01J 31/18 (2006.01); B01J 23/72 (2006.01); C07D 249/06 (2006.01); C07D 311/12 (2006.01); C07D 405/04 (2006.01);
U.S. Cl.
CPC ...
B01J 31/1805 (2013.01); B01J 23/72 (2013.01); B01J 31/181 (2013.01); C07D 249/06 (2013.01); C07D 311/12 (2013.01); C07D 405/04 (2013.01); B01J 2531/16 (2013.01);
Abstract

This invention provides a method for preparing a 1,2,3-triazole compound comprising contacting an organic azide with a 2-substituted-1-haloalkyne, in the presence of a copper catalyst and a copper-coordinating ligand (preferably a tertiary amine) in a liquid reaction medium, thereby forming a 1,4,5-substituted-1,2,3-triazole compound including a halo substituent at the 5-position of the triazole, the organic portion of the organic azide at the 1-position of the triazole, and the substituent of the 1-iodoalkyne at the 4-position of the triazole. A method for preparing 1-iodoalkynes is also provided.


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