The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 04, 2014

Filed:

Jul. 22, 2011
Applicants:

Yoshio Nishiguchi, Iruma-gun, JP;

Yasuo Hibino, Shiki, JP;

Inventors:

Yoshio Nishiguchi, Iruma-gun, JP;

Yasuo Hibino, Shiki, JP;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 17/08 (2006.01); C07C 17/25 (2006.01); C07C 17/383 (2006.01); C07C 17/20 (2006.01); C07C 17/21 (2006.01); C07C 17/38 (2006.01);
U.S. Cl.
CPC ...
C07C 17/38 (2013.01); C07C 17/25 (2013.01); C07C 17/383 (2013.01); C07C 17/206 (2013.01); C07C 17/21 (2013.01);
Abstract

A process for dehydrating a hydrofluorocarbon or hydrochlorofluorocarbon, which can be done by simple equipment, and a continuous process of producing 1,3,3,3-tetrafluoropropene using the dehydration process. The dehydration process includes cooling the hydrofluorocarbon or hydrochlorofluorocarbon in gaseous form containing water with a heat exchanger, thereby condensing and liquefying the hydrofluorocarbon or hydrochlorofluorocarbon while freezing and solidifying the water. The 1,3,3,3-tetrafluoropropene production method includes a first step for fluorinating 1-chloro-3,3,3-trifluoropropene with hydrogen fluoride to obtain a mixture of 1,3,3,3-tetrafluoropropene, unreacted 1-chloro-3,3,3-trifluoropropene, hydrogen fluoride, hydrogen chloride and by-products, or dehydrofluorinating 1,1,1,3,3-pentafluoropropane to obtain a mixture of 1,3,3,3-tetrafluoropropene, unreacted 1,1,1,3,3-pentafluoropropane and by-products, a second step for removing acidic components, a third step for dehydrating the 1,3,3,3-tetrafluoropropene by the above dehydration process, and a fourth step for purifying the 1,3,3,3-tetrafluoropropene by distillation.


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