The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 11, 2003

Filed:

Nov. 07, 2000
Applicant:
Inventors:

Jan Pieter Van Der Lugt, Amersfoort, NL;

Jan Matthijs Jetten, Zeist, NL;

Arie Cornelis Besemer, Amerongen, NL;

Hendrik Arend Van Doren, Amersfoort, NL;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C08B 3/118 ; C07H 1/00 ; C07G 1/700 ; C07C 4/500 ;
U.S. Cl.
CPC ...
C08B 3/118 ; C07H 1/00 ; C07G 1/700 ; C07C 4/500 ;
Abstract

Primary alcohols, especially in carbohydrates, can be selectively oxidized to aldehydes and carboxylic acids in a low-halogen process by using a peracid in the presence of a catalytic amount of a di-tertiary-alkyl nitroxyl (TEMPO) and a catalytic amount of halide. The halide is preferably bromide and the process can be carried out at nearly neutral to moderately alkaline pH (5-11). The peracid can be produced or regenerated by means of hydrogen peroxide or oxygen. The process is advantageous for producing uronic acids and for introducing aldehyde groups which are suitable for crosslinking and derivatization.


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