Method for etching a wafer edge using a potassium-based chemical oxidizer in the presence of hydrofluoric acid

Abstract

A method for fabricating wafers is provided that uses a potassium-based oxidizer in the presence of hydrofluoric acid as the chemical etchant for etching the wafer edge. The potassium-based chemical etchant is preferably potassium permanganate KMnO that is mixed with hydrofluoric acid such that the ratio of hydrofluoric acid to potassium permanganate is between 2:1 and 4:1. The method for fabricating wafers initially divides a crystal ingot into a plurality of wafers before grinding the wafer edge to size and shape the wafer. The wafer can then be subjected to alkaline cleaning and acid etching. After a polysilicon layer is deposited on the wafer for gettering purposes and a silicon dioxide back seal layer, if any, is deposited, the wafer is then etched with the potassium-based chemical oxidizer in the presence of hydrofluoric acid to oxidize and remove the polysilicon layer and any silicon dioxide layer from the edge. The wafer is then rinsed and thermally annealed prior to undergoing edge polishing. In order to concentrate the potassium-based chemical etchant on the wafer edge, the opposed major surfaces can be covered, such as by being stacked in an alternating fashion with spacers. As such, the wafer edge can be reliably formed in an efficient and safe manner.