The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 30, 2024

Filed:

Nov. 06, 2020
Applicant:

Empa Eidgenoessische Materialpruefungs- Und Forschungsanstalt, Duebendorf, CH;

Inventors:

Shanyu Zhao, Duebendorf, CH;

Gilberto De Freitas Siqueira, Zurich, CH;

Wim Malfait, Zurich, CH;

Matthias Koebel, Bruettisellen, CH;

Christopher Ubert, Broadview Heights, OH (US);

David Norris, Munich, DE;

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C01B 33/16 (2006.01); B33Y 10/00 (2015.01); B33Y 40/20 (2020.01); B33Y 70/00 (2020.01); C01B 33/158 (2006.01); C09D 11/033 (2014.01); C09D 11/037 (2014.01); C09D 11/322 (2014.01); C09D 11/36 (2014.01);
U.S. Cl.
CPC ...
C01B 33/1585 (2013.01); B33Y 10/00 (2014.12); B33Y 40/20 (2020.01); B33Y 70/00 (2014.12); C09D 11/033 (2013.01); C09D 11/037 (2013.01); C09D 11/322 (2013.01); C09D 11/36 (2013.01);
Abstract

An ink composition for additive manufacture of silica aerogel objects essentially consists of a gellable silica sol containing an admixture of 30 to 70 vol. % of a mesoporous silica powder in a base solvent. The mesoporous silica powder has a particle size range of 0.001 to 1 mm and a tap density of 30 to 200 kg/m3 and comprises at least 10% by weight of silica aerogel powder. The composition has a yield stress in the range of 30 to 3000 Pa and a viscosity of 5 to 150 Pa·s at a shear rate of 50 s-1. Furthermore, the composition has shear thinning properties defined as a reduction in viscosity by a factor between 10 and 103 for an increase in shear rate by a factor of 104 to 105. A method of additive manufacturing of a three-dimensional silica aerogel object by direct ink writing comprises providing such ink composition, forcing the same through a convergent nozzle, thereby forming a jet of the ink composition which is directed in such manner as to form a three-dimensional object by additive manufacturing. After initiating and carrying out gelation of the gellable silica sol constituting said object, a drying step yields the desired three-dimensional silica aerogel object.


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