The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 28, 2024

Filed:

Oct. 07, 2022
Applicant:

The Government of the United States of America, As Represented BY the Secretary of the Navy, Arlington, VA (US);

Inventor:

James August Ridenour, Arlington, VA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C08K 3/08 (2006.01); B41M 5/28 (2006.01); C07F 15/04 (2006.01);
U.S. Cl.
CPC ...
C07F 15/045 (2013.01);
Abstract

Tunable thermochromic materials comprise a metal salt with a varying proportion of two different anions and an organic ligand. Partial substitution via doping during the initial synthesis with a macro-structurally similar (generating an isostructural material) yet chemically different anion creates a material with altered thermochromic properties. For example, in bromide-doped bis(N,N'-diethylethylenediamine)nickel(II)) tetrafluoroborate; both the tetrafluoroborate (BF4-) and bromide (Br—) derivatives are isostructural. Substitution of BF4- for Br— causes a decrease in the materials' thermochromic transition temperature by approximately 10° C.


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