The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 20, 2024

Filed:

Jan. 27, 2021
Applicant:

Azad Pharma Ag, Schaffhausen, CH;

Inventors:

Hartmut Zinser, Schaffhausen, CH;

Tamar Danielyan, Abovyan, AM;

Meri Grigoryan, Yerevan, AM;

Mariam Gharibyan, Yerevan, AM;

Mikayel Movsisyan, Yerevan, AM;

Kristine Nerkararyan, Yerevan, AM;

Assignee:

AZAD PHARMA AG, Schaffhausen, CH;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 489/12 (2006.01); C07B 49/00 (2006.01); C07B 43/08 (2006.01); C07B 43/04 (2006.01); C07B 31/00 (2006.01); C07B 37/12 (2006.01); C07D 498/12 (2006.01); A61P 25/36 (2006.01); A61P 25/04 (2006.01);
U.S. Cl.
CPC ...
C07D 489/12 (2013.01); A61P 25/04 (2018.01); A61P 25/36 (2018.01); C07B 31/00 (2013.01); C07B 37/12 (2013.01); C07B 43/04 (2013.01); C07B 43/08 (2013.01); C07B 49/00 (2013.01); C07D 498/12 (2013.01);
Abstract

The present invention relates to a novel route of synthesis for the opioid receptor antagonist Buprenorphine or a pharmaceutically acceptable salt thereof, starting from thebaine, wherein the route comprises the reaction of thebaine with a dienophile; forming an alkylated reaction product by reaction with a Grignard-reagent; formation of an cyanamide; deprotection of the cyanamide- and the phenolic-oxygen-moiety, wherein the cleavage of one or both groups is performed in the presence of an alkali or alkaline earth sulfide; followed by derivatization with a cyclopropyl-halogen and hydrogenation to yield Buprenorphine.


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