The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 30, 2024

Filed:

Nov. 16, 2022
Applicant:

Entegris, Inc., Billerica, MA (US);

Inventors:

Vagulejan Balasanthiran, Pennsburg, PA (US);

Scott A. Laneman, Vernon Hills, IL (US);

Jon Alkema, Abington, PA (US);

Thomas Kermis, Lansdale, PA (US);

Assignee:

ENTEGRIS, INC., Billerica, MA (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 1/32 (2006.01); C07F 7/08 (2006.01); C07C 13/61 (2006.01); C07C 13/15 (2006.01); C07F 17/00 (2006.01);
U.S. Cl.
CPC ...
C07C 1/326 (2013.01); C07C 13/15 (2013.01); C07C 13/61 (2013.01); C07F 7/08 (2013.01); C07F 7/0805 (2013.01); C07F 17/00 (2013.01);
Abstract

The disclosure provides methodology for the synthesis of mono-alkylated cyclopentadiene structures, which can be obtained via fulvene intermediates. In one embodiment, the cyclopentadiene ring is substituted with a trialkylsilyl moiety, which enables the further reaction with certain metal halides to form metal adducts. For example, the monoalkyl cyclopentadienes substituted with a trimethylsilyl group can be reacted with TiClto provide R*CpTiClcomplexes, wherein R* is a group of the formula wherein Rand Rare as defined herein.


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