The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 28, 2023

Filed:

Oct. 30, 2019
Applicants:

China Petroleum & Chemical Corporation, Beijing, CN;

Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation, Beijing, CN;

Inventors:

Hongfei Wu, Beijing, CN;

Mingfang Zheng, Beijing, CN;

Songshuang Hu, Beijing, CN;

Tonglin Li, Beijing, CN;

Jun Liu, Beijing, CN;

Ke Xu, Beijing, CN;

Xiaoqing Wang, Beijing, CN;

Feng Pan, Beijing, CN;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 31/24 (2006.01); C07C 2/36 (2006.01);
U.S. Cl.
CPC ...
B01J 31/2409 (2013.01); C07C 2/36 (2013.01); C07C 2531/24 (2013.01);
Abstract

A halogen-containing compound represented by a formula I and a use thereof as a ligand of an ethylene oligomerization catalyst composition, an ethylene oligomerization catalyst composition comprising the halogen-containing compound, and an ethylene oligomerization method, ethylene trimerization method and ethylene tetramerization method using the catalyst composition are provided. Serving as the ligand of the ethylene oligomerization catalyst, the halogen-containing polymer may effectively improve the catalytic performance of a catalyst system, especially by displaying a significantly improved catalytic performance in an ethylene oligomerization reaction. The maximum catalyst activity may exceed 4×10g·mol(Cr)·h, and the total selectivity of 1-hexene and 1-octene exceeds 92 wt %. In a C6 product, the content of 1-hexene may reach about 97%, and in a C8 product, the content of 1-octene may reach more than 98%.


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