The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 09, 2021

Filed:

Jan. 15, 2019
Applicant:

Hitachi Metals, Ltd., Tokyo, JP;

Inventors:

Takeshi Shimada, Tokyo, JP;

Nan Wang, Tokyo, JP;

Michiko Matsuda, Tokyo, JP;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01L 35/18 (2006.01); B22F 3/10 (2006.01); B22F 9/04 (2006.01); C01G 51/00 (2006.01); C22C 12/00 (2006.01); H01L 35/32 (2006.01); H01L 35/34 (2006.01); B82Y 30/00 (2011.01);
U.S. Cl.
CPC ...
H01L 35/18 (2013.01); B22F 3/1007 (2013.01); B22F 9/04 (2013.01); C01G 51/006 (2013.01); C22C 12/00 (2013.01); H01L 35/32 (2013.01); H01L 35/34 (2013.01); B22F 2009/048 (2013.01); B82Y 30/00 (2013.01); C01P 2002/01 (2013.01); C01P 2002/70 (2013.01); C01P 2004/03 (2013.01); C01P 2004/04 (2013.01);
Abstract

A thermoelectric conversion material having a high dimensionless figure of merit ZT includes: a large number of polycrystalline grains which include a skutterudite-type crystal structure containing Yb, Co, and Sb; and an intergranular layer which is between the neighboring polycrystalline grains and includes crystals in which an atomic ratio of O to Yb is more than 0.4 and less than 1.5. A method for manufacturing a thermoelectric conversion material includes: a weighing step; a mixing step; a ribbon preparation step by rapidly cooling and solidifying a melt of the raw materials by using a rapid liquid cooling solidifying method; a first heat treatment step including heat treating in an inert atmosphere with an adjusted oxygen concentration; a second heat treatment step including heat treating in a reducing atmosphere; and manufacturing the thermoelectric conversion material by a pressure sintering step in an inert atmosphere.


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