The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 24, 2021

Filed:

Oct. 11, 2018
Applicants:

L'air Liquide, Société Anonyme Pour L'etude ET L'exploitation Des Procédés Georges Claude, Paris, FR;

American Air Liquide, Inc., Fremont, CA (US);

Inventors:

Grigory Nikiforov, Bridgewater, NJ (US);

Guillaume Husson, Newark, DE (US);

Gennadiy Itov, Flemington, NJ (US);

Yang Wang, Garnet Valley, PA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C01B 33/04 (2006.01); B01J 31/02 (2006.01);
U.S. Cl.
CPC ...
C01B 33/04 (2013.01); B01J 31/0275 (2013.01); C01B 33/046 (2013.01);
Abstract

Synthesis of silanes with more than three silicon atoms are disclosed (i.e., (SiHwith n=4-100). More particularly, the disclosed synthesis methods tune and optimize the isomer ratio by selection of process parameters such as temperature, residence time, and the relative amount of starting compounds, as well as selection of proper catalyst. The disclosed synthesis methods allow facile preparation of silanes containing more than three silicon atoms and particularly, the silanes containing preferably one major isomer. The pure isomers and isomer enriched mixtures are prepared by catalytic transformation of silane (SiH), disilane (SiH), trisilane (SiH), and mixtures thereof.


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