The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 08, 2021

Filed:

Mar. 06, 2020
Applicant:

Korea Advanced Institute of Science and Technology, Daejeon, KR;

Inventors:

Minkee Choi, Daejeon, KR;

Woosung Choi, Daejeon, KR;

Chaehoon Kim, Daejeon, KR;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 20/26 (2006.01); B01J 20/04 (2006.01); B01J 20/10 (2006.01); B01J 20/22 (2006.01); B01J 20/28 (2006.01); B01J 20/32 (2006.01); B01D 53/02 (2006.01); B01D 53/04 (2006.01);
U.S. Cl.
CPC ...
B01J 20/265 (2013.01); B01D 53/02 (2013.01); B01D 53/0462 (2013.01); B01J 20/048 (2013.01); B01J 20/103 (2013.01); B01J 20/223 (2013.01); B01J 20/28021 (2013.01); B01J 20/28071 (2013.01); B01J 20/28073 (2013.01); B01J 20/28076 (2013.01); B01J 20/3204 (2013.01); B01J 20/328 (2013.01); B01J 20/3236 (2013.01); B01J 20/3265 (2013.01); B01J 20/3289 (2013.01); B01J 20/3293 (2013.01); B01D 2253/102 (2013.01); B01D 2253/106 (2013.01); B01D 2253/108 (2013.01); B01D 2253/202 (2013.01); B01D 2253/204 (2013.01); B01D 2253/25 (2013.01); B01D 2253/311 (2013.01); B01D 2257/302 (2013.01); B01D 2257/504 (2013.01); B01D 2258/0283 (2013.01);
Abstract

A core-shell type amine-based carbon dioxide adsorbent is described, including a chelating agent resistant to oxygen and sulfur dioxide, to inhibit oxidative decomposition of amine. As a core, a porous support is employed on which an amine compound is immobilized, and, as a shell, an amine layer resistant to inactivity by sulfur dioxide is utilized. Such adsorbent exhibits high oxidation resistance because the chelating agent functions to remove a variety of transition metal impurities catalytically acting on amine oxidation. In addition, the sulfur dioxide-resistant amine layer of the shell selectively adsorbs sulfur dioxide to protect the amine compound of the core and, at the same time, the amine compound of the core selectively adsorbs only carbon dioxide. Sulfur dioxide adsorbed on the shell is readily desorbable therefrom at about 110° C. and thus remarkably improved regeneration stability is obtained during temperature-swing adsorption (TSA) processes in which sulfur dioxide is present.


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