The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 18, 2020

Filed:

Dec. 03, 2016
Applicant:

Soochow University, Suzhou, CN;

Inventors:

Aijuan Gu, Suzhou, CN;

Jiatao Miao, Suzhou, CN;

Guozheng Liang, Suzhou, CN;

Li Yuan, Suzhou, CN;

Assignee:

SOOCHOW UNIVERSITY, Suzhou, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 59/24 (2006.01); C08G 59/68 (2006.01); C08G 59/26 (2006.01); C07D 307/68 (2006.01); C07D 407/14 (2006.01); C07D 301/14 (2006.01); C07D 303/02 (2006.01);
U.S. Cl.
CPC ...
C08G 59/24 (2013.01); C07D 301/14 (2013.01); C07D 303/02 (2013.01); C07D 307/68 (2013.01); C07D 407/14 (2013.01); C08G 59/245 (2013.01); C08G 59/26 (2013.01); C08G 59/686 (2013.01);
Abstract

The present invention discloses a biomass-based epoxy resin and preparation method thereof; under conditions of N,N-dimethylformamide as a catalyst, 2,5-furandicarboxylic acid and thionyl chloride are acylated to obtain 2,5-furan diformyl chloride; then it is dissolved with dichloromethane; under tertiary amine conditions an esterification reaction takes place, and bis(4-allyl-2-methoxyphenyl)furan-2,5-dicarboxylic acid ester is thus obtained; by means of meta-chloroperoxybenzoic acid, its unsaturated double bond is epoxidized to obtain a biomass-based epoxy resin. The process of the present invention is simple; the raw materials come from biomass 2,5-furandicarboxylic acid and eugenol; in comparison with bisphenol-A epoxy resin based on petroleum and coal resources, the raw materials are green and renewable, and are advantageous to reducing the consumption of renewable resources with regard to polymeric material. The obtained cured epoxy resin has excellent thermal properties and modulus, and has broad prospects for application.


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