The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 30, 2019

Filed:

Dec. 30, 2016
Applicant:

L'air Liquide, Societe Anonyme Pour L'etude ET L'exploitation Des Procedes Georges Claude, Paris, FR;

Inventors:

Daehyeon Kim, Seoul, KR;

Satoko Gatineau, Seoul, KR;

Wontae Noh, Seoul, KR;

Julien Gatineau, Seoul, KR;

Jean-Marc Girard, Versailles, FR;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07F 7/00 (2006.01); C07F 17/00 (2006.01); C23C 16/18 (2006.01); C23C 16/455 (2006.01);
U.S. Cl.
CPC ...
C07F 7/00 (2013.01); C07F 17/00 (2013.01); C23C 16/18 (2013.01); C23C 16/45525 (2013.01);
Abstract

Group 4 transition metal-containing film forming compositions are disclosed. The Group 4 transition metal-containing film forming compositions comprise Group 4 transition metal precursors having the formula L-M-CR-[(ER)—NR]—, wherein M is Ti, Zr, or Hf bonded in an ηbonding mode to the Cp group; each E is independently C, Si, B or P; each R is independently a hydrogen or a C-Chydrocarbon group; and each L is independently a −1 anionic ligand selected from the group consisting of NR', OR′, Cp, amidinate, β-diketonate, or keto-iminate, wherein R′ is a H or a C-Chydrocarbon group and adjacent R′s may be joined to form a hydrocarbyl ring; provided that at least one R on the Cp is Cto C. Also disclosed are methods of synthesizing and using the disclosed precursors to deposit Group 4 transition metal-containing films on one or more substrates via vapor deposition processes.


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