Lsi Logic Corporation

Lsi Corporation

Wei-Jen Hsia

Wilbur G Catabay

Joe W Zhao

Zhihai Wang

Hong-Qiang Lu

Wai Lo

Weidan Li

Shiqun Gu

Sey-Shing Sun

Richard D Schinella

Valeriy K Sukharev

Kai Zhang

Verne C Hornback

Hong Lin

Thomas G Mallon

Hao Cui

Chi-Yi Kao

Atsushi Shimoda

Philippe Schoenborn

Dung-Ching Perng

Hongqiang Lu

Yong-Bae Kim

Masaichi Eda

Alex Kabansky

Kiran Kumar

John Rongxiang Hu

Yongbae Kim

Sang-Yun Lee

Hiroaki Takikawa

Linggian Qian

Hong Qiang

Warren Uesato

Provided is a process for forming a barrier film to prevent resist poisoning in a semiconductor device by depositing a second nitrogen-free barrier layer on top of a first barrier layer containing nitrogen. A low-k dielectric layer is formed over the second barrier layer. This technique maintains the low electrical leakage characteristics of the first barrier layer and reduces nitrogen poisoning of a photoresist layer subsequently applied.

Dual layer barrier film techniques to prevent resist poisoning

The present invention provides a method of forming a high-k dielectric layer on a semiconductor wafer. A metal silicate dielectric layer is initially deposited on the wafer. A dopant having dissociable oxygen is introduced into the metal silicate on the wafer. According to one embodiment the metal silicate comprises a group IV metal and the dopant is an oxide of one of an alkaline metal and an alkaline earth metal. According to another embodiment the metal silicate comprises a group III metal.

Incorporating dopants to enhance the dielectric properties of metal silicates

An improvement to a method of forming an integrated circuit. An etch stop layer is formed to overlie the front end processing layers of the integrated circuit. Support structures are formed that are disposed so as to support electrically conductive interconnects on various levels of the integrated circuit. Substantially all of the non electrically conductive layers above the etch stop layer that were formed during the fabrication of the interconnects are removed.

Interconnect dielectric tuning

A method of forming a planarized layer on a substrate, where the substrate is cleaned, and the layer is formed having a surface with high portions and low portions. A resistive mask is formed over the low portions of the layer, but not over the high portions of the layer. The surface of the layer is etched, where the high portions of the layer are exposed to the etch, but the low portions of the layer underlying the resistive mask are not exposed to the etch. The etch of the surface of the layer is continued until the high portions of the layer are at substantially the same level as the low portions of the layer, thereby providing an initial planarization of the surface of the layer. The resistive mask is removed from the surface of the layer, and all of the surface of the layer is planarized to provide a planarized layer.

Planarization with reduced dishing

A process for forming an integrated circuit structure comprises forming a layer of low k dielectric material over a previously formed integrated circuit structure, and treating the upper surface of the layer of low k dielectric material with a plasma to form a layer of densified dielectric material over the remainder of the underlying layer of low k dielectric material, forming a second layer of low k dielectric material over the layer of densified dielectric material, and treating this second layer of low k dielectric material to form a second layer of densified dielectric material over the second layer of low k dielectric material. The layer or layers of densified dielectric material formed from the low k dielectric material provide mechanical support and can then function as etch stop and mask layers for the formation of vias and/or trenches.

Plasma treatment of low dielectric constant dielectric material to form structures useful in formation of metal interconnects and/or filled vias for integrated circuit structure

A three step process for planarizing an integrated circuit structure comprising one or more dielectric layers having trench and/or via openings therein lined with a layer of electrically conductive barrier liner material and filled with copper filler material. Sufficient excess copper (formed over the barrier liner portions on the top surface of the dielectric layer) is removed in an initial chemical mechanical polish (CMP) step to provide a planarized copper layer with a global planarity of about 20 nm to about 30 nm. The remainder of the excess copper over the portion of the barrier liner material lying on the top surface of the dielectric layer is then removed by electropolishing the structure, in a second step, until all of the excess copper over the portion of the barrier liner material lying on the top surface of the dielectric layer is removed. In a third step, all remaining portions of the diffusion barrier liner on the upper surface of the low k dielectric layer are then removed using a dry etching process selective to copper and the dielectric layer until all of the portions of the barrier layer over the top surface of the dielectric layer are removed; whereby the integrated circuit structure may be planarized by removal of all of the copper layer and barrier layer from the top surface of the dielectric layer while inhibiting dishing and/or erosion of the surface of copper filler material in the opening, and without risking distortion and/or delamination by the harsh effects of excessive CMP processing.

Process for planarizing upper surface of damascene wiring structure for integrated circuit structures

A capping layer of an insulator such as silicon oxynitride is formed over horizontally closely spaced apart metal lines on an oxide layer of an integrated circuit structure formed on a semiconductor substrate. Low k silicon oxide dielectric material which exhibits void-free deposition properties in high aspect ratio regions between the closely spaced apart metal lines is then deposited over and between the metal lines and over the silicon oxynitride caps on the metal lines. After the formation of such void-free low k silicon oxide dielectric material between the closely spaced apart metal lines and the silicon oxynitride caps thereon, the structure is planarized to bring the level of the low k silicon oxide dielectric material down to the level of the tops of the silicon oxynitride caps on the metal lines. A further layer of standard k silicon oxide dielectric material is then formed over the planarized void-free low k silicon oxide dielectric layer and the silicon oxynitride caps. Vias are then formed through the standard k silicon oxide dielectric layer and the silicon oxynitride caps down to the metal lines. Since the vias are not formed through the low k silicon oxide dielectric material, formation of the vias does not contribute to poisoning of the vias. However, the presence of the low k silicon oxide dielectric material between the horizontally closely spaced apart metal lines reduces the horizontal capacitance between such metal lines.

Integrated circuit structure having low dielectric constant material and having silicon oxynitride caps over closely spaced apart metal lines

Plasma treatment of low dielectric constant dielectric material to form structures useful in formation of metal interconnects and/or filled vias for intergrated circuit structure

The present invention is directed to a semiconductor structure including a semiconductor substrate having at least one overlying layer formed thereon. The at least one overlying layer including at least one layer of dielectric material. The at least one layer of dielectric material including a protected region having a first dielectric constant and another porous region having a second dielectric constant wherein the value for the second dielectric constant is less than the first dielectric constant. The porous region having been formed by the implantation of a porosity inducing material into the porous region and subsequent annealing. A method for forming such structures is also included.

Method and structure for forming dielectric layers having reduced dielectric constants

An integrated circuit structure is disclosed wherein the capacitance between nearby conductive portions may be lowered using carbon-containing low k silicon oxide dielectric material, without contributing to the problem of via poisoning, by careful control of the carbon content of the dielectric material in two regions of the integrated circuit structure. The first region comprises the region between adjacent raised conductive lines formed over an underlying insulation layer, where undesirable capacitance may be formed horizontally between such adjacent conductive lines, while the second region comprises the region above the raised conductive lines where vias are normally formed extending upward from the raised conductive lines through the dielectric layer to an overlying layer of metal interconnects. In one embodiment, the carbon-containing low k silicon oxide dielectric material used in the first region between adjacent raised conductive lines has a high carbon content to provide maximum reduction of the dielectric constant of the dielectric material for maximum reduction in the horizontal capacitance developed between horizontally adjacent lines, while the carbon-containing low k silicon oxide dielectric material used in the second region above the raised conductive lines has a reduced carbon content to mitigate poisoning of vias formed through the dielectric material in this second region. In another embodiment both the first and second regions have the same or similar reduced carbon content in the carbon-containing low k silicon oxide dielectric material used in both of the respective first and second regions to thereby provide a carbon content sufficient to lower the undesirable capacitance formed horizontally between said adjacent raised conductive lines in said first region, but insufficient to cause via poisoning in vias formed in said second region.

Low dielectric constant silicon oxide-based dielectric layer for integrated circuit structures having improved compatibility with via filler materials, and method of making same

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Sunnyvale, CA, United States of America

Wei-Jen Hsia