International Business Machines Corporation

Stmicroelectronics Gmbh

Tokyo Electron Limited

Globalfoundries Inc.

Lisa F Edge

Hemanth Jagannathan

Vamsi Krishna Paruchuri

Balasubramanian S Haran

Paul Charles Jamison

Bruce Bennett Doris

Kangguo Cheng

Alexander Reznicek

Pouya Hashemi

Takashi Ando

David V Horak

Nicolas J Loubet

Vijay Narayanan

Qing Liu

Sanjay C Mehta

Sufi Zafar

Prasanna Khare

Changhwan Choi

Jason E Cummings

Stephane Allegret-Maret

Ali Khakifirooz

Stephen W Bedell

Pranita Kerber

Robert Daniel Clark

Qiqing Christine Ouyang

James J Demarest

Shariq Siddiqui

Gangadhara Raja Muthinti

Nathaniel C Berliner

Raymond J Donohue

An electrical device that includes a p-type semiconductor device having a p-type work function gate structure including a first high-k gate dielectric, a first metal containing buffer layer, a first titanium nitride layer having a first thickness present on the metal containing buffer layer, and a first gate conductor contact. A mid gap semiconductor device having a mid gap gate structure including a second high-k gate dielectric, a second metal containing buffer layer, a second titanium nitride layer having a second thickness that is less than the first thickness present, and a second gate conductor contact. An n-type semiconductor device having an n-type work function gate structure including a third high-k gate dielectric present on a channel region of the n-type semiconductor device, a third metal containing buffer layer on the third high-k gate dielectric and a third gate conductor fill present atop the third metal containing buffer layer.

Complementary metal oxide semiconductor replacement gate high-k metal gate devices with work function adjustments

Multiple threshold voltage devices on hybrid oriented substrates, and methods of manufacturing same are disclosed. A method for manufacturing a semiconductor device comprises performing a single epitaxy step on a hybrid orientation substrate including a first region having a first crystallographic orientation and a second region having a second crystallographic orientation different from the first crystallographic orientation, wherein the single epitaxy step forms a first layer disposed on the first region and a second layer disposed on the second region, the first layer has the first crystallographic orientation and a first composition, and the second layer has the second crystal orientation and a second composition different from the first composition.

Channel SiGe devices with multiple threshold voltages on hybrid oriented substrates, and methods of manufacturing same

Complementary metal oxide semiconductor replacement gate high-K metal gate devices with work function adjustments

In an embodiment, a method comprises fitting a spectroscopic data of a layer in a layered structure to a dielectric function having a real part and an imaginary part; confirming that the dielectric function is physically possible; based on the dielectric function not being physically possible, repeating the fitting the spectroscopic data, or, based on the dielectric function being physically possible, defining an n degree polynomial to the dielectric function; determining a second derivative and a third derivative of the n degree polynomial; equating the second derivative to a first governing equation and the third derivative to a second governing equation and determining a constant of the first governing equation and the second governing equation; and based on the key governing equations, determining one or more of a band gap, a thickness, and a concentration of the layer.

Method for characterization of a layered structure

A method is provided that includes providing a material stack of, from bottom to top, a relaxed and n-type doped silicon germanium alloy layer and a relaxed silicon germanium alloy layer, each layer having a uniform germanium content, on a surface of a relaxed and graded silicon germanium alloy buffer layer that is located within a pFET device region of a semiconductor substrate. Next, the relaxed silicon germanium alloy layer is patterned to provide at least one relaxed silicon germanium alloy fin having the uniform germanium content on the relaxed and n-type doped silicon germanium alloy layer. A strained germanium layer is then formed surrounding the at least one relaxed silicon germanium alloy fin. A portion of the strained germanium layer and the at least one relaxed silicon germanium alloy fin can be used as composited channel material for fabricating a pFinFET device.

Structure and method for highly strained germanium channel fins for high mobility pFINFETs

A substrate is provided, having formed thereon a first region and a second region of a complementary type to the first region. A gate dielectric is deposited over the substrate, and a first full metal gate stack is deposited over the gate dielectric. The first full metal gate stack is removed over the first region to produce a resulting structure. Over the resulting structure, a second full metal gate stack is deposited, in contact with the gate dielectric over the first region. The first and second full metal gate stacks are encapsulated.

Integration of multiple threshold voltage devices for complementary metal oxide semiconductor using full metal gate

Equivalent oxide thickness (EOT) scaled high k/metal gate stacks are provided in which the capacitance bottleneck of the interfacial layer is substantially eliminated, with minimal compromise on the mobility of carriers in the channel of the device. In one embodiment, the aforementioned EOT scaled high k/metal gate stacks are achieved by increasing the dielectric constant of the interfacial layer to a value that is greater than the originally formed interfacial layer, i.e., the interfacial layer prior to diffusion of a high k material dopant element therein. In another embodiment, the aforementioned scaled high k/metal gate stacks are achieved by eliminating the interfacial layer from the structure. In yet another embodiment, the aforementioned high k/metal gate stacks are achieved by both increasing the dielectric constant of the interfacial layer and reducing/eliminating the interfacial layer.

Structure and method to obtain EOT scaled dielectric stacks

A memory device may include a semiconductor substrate, and a memory transistor in the semiconductor substrate. The memory transistor may include source and drain regions in the semiconductor substrate and a channel region therebetween, and a gate stack. The gate stack may include a first dielectric layer over the channel region, a first diffusion barrier layer over the first dielectric layer, a first electrically conductive layer over the first diffusion barrier layer, a second dielectric layer over the first electrically conductive layer, a second diffusion barrier layer over the second dielectric layer, and a second electrically conductive layer over the second diffusion barrier layer. The first and second dielectric layers may include different dielectric materials, and the first diffusion barrier layer may be thinner than the second diffusion barrier layer.

Memory device having multiple dielectric gate stacks and related methods

A memory device may include a semiconductor substrate, and a memory transistor in the semiconductor substrate. The memory transistor may include source and drain regions in the semiconductor substrate and a channel region therebetween, and a gate stack having a first dielectric layer over the channel region, a second dielectric layer over the first dielectric layer, a first diffusion barrier layer over the second dielectric layer, a first electrically conductive layer over the first diffusion barrier layer, a second diffusion barrier layer over the first electrically conductive layer, and a second electrically conductive layer over the second diffusion barrier layer. The first and second dielectric layers may include different dielectric materials, and the first diffusion barrier layer may be thinner than the second diffusion barrier layer.

Memory device having multiple dielectric gate stacks with first and second dielectric layers and related methods

A structure and method for forming a dual metal fill and dual threshold voltage for replacement gate metal devices is disclosed. A selective deposition process involving titanium and aluminum is used to allow formation of two adjacent transistors with different fill metals and different workfunction metals, enabling different threshold voltages in the adjacent transistors.

Dual metal fill and dual threshold voltage for replacement gate metal devices

A method of forming a semiconductor device is provided where in one embodiment an STI fill is recessed below the pad nitride and pad oxide layers, to a level substantially coplanar with the top surface of the substrate. A thin (having a thickness in the range of about 10 &#x212b;-100 &#x212b;) wet etch resistant layer is formed in contact with and completely covering at least the top surface of the recessed STI fill material. The thin wet etch resistant layer is more resistant to a wet etch process than at least the pad oxide layer. The thin wet etch resistant layer may be a refractory dielectric material, or a dielectric such as HfO, AlO, ZrO, HfZrO, and HfSiO. The inventive wet etch resistant layer improves the wet etch budget of subsequent wet etch processing steps.

Method to improve wet etch budget in FEOL integration

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Watervliet, NY, United States of America

Lisa F Edge