Westfalia Separator Ag

Dr. Frische Gmbh

T+t Oleochemie Gmbh

Karlheinz Brunner

Rainer Frische

Rainer Ricker

Bernd Best

Dirk Kilian

Katja Hegwein

Willi Ostkamp

Joachim Seemann

Friedrich Wibbelt

A method for the production of fatty acid esters of primary and/or secondary alcohols from raw, unpurified oils or fats containing free fatty acids and slimy substances or from waste oils loaded with free fatty acids from the food industry. Acidic catalytic esterification is performed on the free fatty acids along with extensive deactivation of the slimy substances present with respect to the disadvantageous emulsion-forming property thereof, whereby a water-free primary and/or secondary alcohol and a highly acidic hygroscopic catalyst are added to the starting substance in the form of crude oil or fat or waste oil, the reaction product is rinsed with glycol from a prior alkaline transesterification, whereupon alkaline transesterification occurs for the unmodified remaining glyceridically bound fatty acids in the reaction product of the acidic-catalytic esterification process.

Method for the production of fatty acid esters

A method for pretreating crude oils and fats for subsequent alkaline transesterification with primary and/or secondary alcohols. The raw oil or fat loaded with slimy substances is treated with a mixture used at 0.15 wt. % in relation to the oil or fat comprising an alcohol and concentrated acid, and preferably is subsequently rinsed with an alkaline glycerol phase arising from an alkaline transesterification reaction of the above-mentioned type. After the rinsing process, the glycerol phase which is loaded with slimy substances and soaps of free fatty acids is separated as a heavy phase of neutral oil liberated from free fatty acids.

Method for pretreating crude oils and raw fats for the production of fatty acid esters

Method for the enzymatic splitting of oils and fats for obtaining fatty acids and glycerol by using lipases being added to a mixture containing an oil or fat and water, wherein the splitting reaction is performed only up to a splitting degree at which slowing-down of the splitting reaction is still below a preset value using discontinuously operated loop reactors, wherein the fatty acids to be obtained are separated from the reaction mixture that is only partially split, by first separating an aqueous glycerol-containing phase from a partially split organic phase containing split fatty acids, in a self-cleaning centrifugal separator and, afterwards, the fatty acids are separated from the partially split organic phase and the residue of the organic phase freed from the free fatty acids is fed back into the splitting process.

Method for enzymatic splitting of oils and fats

A process for carrying out a multi-phase reaction in a continuously operated tube reactor operated according to the counter current principle in which reactor components of a liquid phase flowing downwards as a thin film in said tube reactor and components of a continuous gas flowing upward in said tube reactor are brought to material transfer, or reaction respectively. The gas phase is pulsed, by repeated temporary pressure lowering at the gas entry into said tube reactor and/or repeated temporary pressure increase at the gas exit from said tube reactor, to counteract film thickness growth and liquid phase stagnation.

Process for carrying out multi-phase reactions according to the counter current principle of a liquid and gaseous phase and apparatus for carrying out the process

Process for extracting native products which are not water-soluble from

A continuous, completely jacketed countercurrent centrifugal extractor of the type utilized to mix and separate two liquids that have different specific gravities and enter through separate inlets. The extractor has at least one overflow weir in a mixing zone between the inlet for the specifically lighter and the inlet for the specifically heavier liquid phase and a division of the mixing zone into mixing-and-separation compartments. Access channels empty into the vicinity of the inner surface of a drum jacket and into that of the heavier phase, to conduct the lighter phase out of the compartment inside the hub of a conveyor worm into the initial mixing-and-separation compartment. One or more overflow channels also empty into the vicinity of the heavier phase, in the overflow weir to divert the lighter phase separated in the initial mixing-and-separation compartment into another and subsequent mixing-and-separation compartment. The design creates several highly efficient contact points in the vicinity of the mixing zone that enhance the extracting action.

Growing community of inventors

Grosskrotzenburg, Germany

Karlheinz Brunner