Lsi Logic Corporation

Aviza Technology Limited

Jon S Owyang

Sheldon Aronowitz

Nicholas K Eib

Douglas Ticknor Grider

Valeriy K Sukharev

John Haywood

Yoshihide Senzaki

James P Kimball

Sang-In Lee

Aubrey L Helms, Jr

Karem Kapkin

A method of depositing a hafnium-based dielectric film is provided. The method comprises atomic layer deposition using ozone and one or more reactants comprising a hafnium precursor. A semiconductor device is also provided. The device comprises a substrate, a hafnium-based dielectric layer formed atop the substrate, and an interfacial layer formed between the substrate and the hafnium-based dielectric layer, wherein the interfacial layer comprises silicon dioxide and has a crystalline structure.

Atomic layer deposition of hafnium-based high-k dielectric

A crystalline semiconductor gate electrode having a re-entrant geometry and a process for making same are disclosed. The novel gate electrode may be formed from a polysilicon layer on a substrate by first implanting a masked polysilicon layer with a neutral species, i.e., a species which will not introduce a dopant into the polysilicon, such as a Group IV element, e.g., silicon, or a Group VIII element, e.g., argon. The neutral species is implanted into the masked polysilicon layer at an angle to provide a tapered implanted region which undercuts one side of the length (long dimension) of the mask. The substrate may then be rotated 180.degree. and then again implanted to provide a tapered implanted region which undercuts the opposite side of the length of the mask. When gate electrodes with such re-entrant geometry are to be formed on a substrate with their long axes at right angles to one another, i.e., some lying along an X axis in the plane of the masked polysilicon layer on the substrate and others lying along a Y axis in the plane of the masked polysilicon layer on the substrate, the substrate may be rotated 90.degree., rather than 180.degree., between each implantation, and four implantations, rather than two, are performed. After the implantations, the implanted masked polysilicon layer is then subject to an etch, preferably an anisotropic etch, which will remove the unmasked implanted portions of the polysilicon layer, as well as the implanted regions beneath the mask, resulting in a gate electrode with re-entrant or tapered sidewalls, i.e., resembling an inverted trapezoid in cross-section.

Process for forming re-entrant geometry for gate electrode of integrated

Rapid Thermal Processing of a semiconductor wafer is performed by scanning a laser beam across a silicon dioxide film in contact with a surface of the wafer. The silicon dioxide film absorbs the energy from the laser beam and converts the energy to heat. The heat, in turn, is transferred to the wafer. Temperature feedback can be obtained to increase control and uniformity of temperatures across the wafer.

Method of forming a layer and semiconductor substrate

Apparatus for rapid thermal processing of a wafer

A uniformly doped polysilicon gate electrode of an MOS device forming a part of an integrated circuit structure on a semiconductor substrate is formed by first depositing a very thin layer of amorphous or polycrystalline silicon, e.g., from about 2 nm to about 10 nm, over a gate oxide layer. The thin layer of silicon layer is then exposed to a nitrogen plasma formed from N.sub.2 at a power level sufficient to break the silicon--silicon bonds in the thin layer of silicon, but insufficient to cause sputtering of the silicon to cause a barrier layer of silicon and nitrogen to form at the surface of the thin silicon layer. Further silicon, e.g., polysilicon, is then deposited over the barrier layer to the desired thickness of the polysilicon gate electrode. The gate electrode is then conventionally doped, i.e., by implantation followed by furnace annealing, to diffuse and activate the dopant in the polysilicon gate electrode without, however, resulting in penetration of the dopant through the barrier layer into the underlying gate oxide layer or the semiconductor substrate.

Diffusion barrier for polysilicon gate electrode of MOS device in

A method, and resulting product, are disclosed for selectively forming polycrystalline silicon over exposed portions of a single crystal silicon substrate. The method includes inhibiting the formation of such polycrystalline silicon over adjacent silicon oxide surfaces; and the resulting product of such a process. The polycrystalline silicon is selectively deposited over the single crystal silicon substrate by first forming a thin layer of a lattice mismatched material over the single crystal silicon surface, and then depositing a layer of polycrystalline silicon over the lattice mismatched material. Preferably, the thin lattice mismatched layer comprises a silicon/germanium (SiGe) alloy.

Product resulting from selective deposition of polysilicon over single

Rapid thermal processing using a narrowband infrared source and feedback

Process for selective deposition of polysilicon over single crystal

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San Jose, CA, United States of America

Jon S Owyang