Shin-etsu Handotai Co., Ltd.

Isao Yokokawa

Kiyoshi Mitani

Hiroji Aga

Nobuhiko Noto

Masahiro Kato

Shigetoshi Sugawa

Tadahiro Ohmi

Norihiro Kobayashi

Masatake Nakano

Toru Ishizuka

Kiyoshi Demizu

Hiroshi Takeno

Kiyotaka Takano

Satoshi Oka

Naoto Tate

Masayuki Imai

Yasushi Mizusawa

Hiroshi Fujisawa

Shin-ichi Yamaguchi

Shin-Ichi Yamaguchi

A bonded wafer including an ion implantation step using a batch processing ion implanter, wherein the ion implantation step is performed by irradiating a bond wafer with a light element ion beam without forming an insulator film on the bond wafer surface or through an insulator film having a thickness of 50 nm or less formed on the bond wafer surface at an implantation angle inclined from a crystal axis of the bond wafer; and the bond wafer surface is irradiated with the center of the light element ion beam shining at a position on the bond wafer surface shifted from the center of the bond wafer parallel to the center of a rotor by a predetermined amount providing a bonded wafer to prevent degradation of the radial uniformity of ion implantation depth and manufacture a bonded wafer with excellent radial uniformity of thickness of a thin film after delamination.

Method for manufacturing bonded wafer

A method for manufacturing an SOI wafer, including steps of: bonding a bond wafer and a base wafer each composed of a silicon wafer at room temperature with a silicon oxide film interposed therebetween; a thinning the bond wafer; and before the bonding step, cleaning the wafers with a hydrophilic cleaning liquid and drying the cleaned wafers by suction drying or spin drying. After the drying step is ended and before the bonding step is started, the wafers are stored until a state where a bonding speed at which the bonding step is to be performed is 20 mm/second or less. The bonding is performed with the bonding speed of 20 mm/second or less. This provides a method for manufacturing an SOI wafer by which an SOI wafer can be manufactured while generation of outer-peripheral micro voids is suppressed in a simple manner.

Method for manufacturing SOI wafer

A method for producing a bonded SOI wafer, by ion implantation delamination to fabricate a bonded SOI wafer having a BOX layer and a SOI layer on a base wafer. After performing flattening heat treatment in an argon gas-containing atmosphere, sacrificial oxidation treatment adjusts the film thickness of the SOI layer, wherein the film thickness of the BOX layer is 500 nm or more. A sacrificial oxide film is formed so the relationship between the film thickness of the SOI layer on the sacrificial oxidation treatment is performed. The film thickness of the sacrificial oxide film formed by the sacrificial oxidation treatment satisfies 0.9d&#x3e;t&#x3e;0.45d. A method for producing a bonded SOI wafer can prevent the generation of particles from the outermost peripheral part, which is the form of an overhang by flattening heat treatment, of a SOI layer in the production of a bonded SOI wafer.

Method for producing bonded SOI wafer

A method for producing a SOI wafer that includes implanting at least one type of gas ion selected from a hydrogen ion and a rare gas ion from a surface of a bond wafer formed of a silicon single crystal to form an ion implanted layer, bonding the ion-implanted surface of the bond wafer to a surface of a base wafer formed of a silicon single crystal through a silicon oxide film formed on the base wafer surface, delaminating the bond wafer at the ion implanted layer by performing delamination heat treatment to fabricate a SOI wafer having a buried oxide film layer and a SOI layer on the base wafer, and performing flattening heat treatment on the SOI wafer in an atmosphere containing argon gas.

Method for producing SOI wafer

A method for manufacturing bonded wafer including: producing bonded wafer having thin-film on its base wafer by an ion implantation delamination method, and reducing film thickness of the thin-film, wherein the step of reducing the film thickness includes a stage of reducing the film thickness by sacrificial oxidation treatment or vapor phase etching, wherein the method for manufacturing bonded wafer further includes a cleaning step of cleaning the bonded wafer exposing the delamination surface just before the step of reducing the film thickness, wherein the cleaning step includes a stage of performing a wet cleaning by successively dipping the bonded wafer to plural of cleaning baths, and wherein the wet cleaning is performed without applying ultrasonic in each of the cleaning baths in the wet cleaning. The method enables to clean bonded wafer exposing delamination surface remaining damage of ion implantation using a cleaning line in a strict control level.

A method of producing a bonded wafer in which wafers each having a cutout portion are used as a bond wafer and a base wafer, and either or both of settings of an ion implanter with which ions are implanted and conditions of the ion implantation are adjusted in the step of implanting the ions such that a cutout portion of either or both of the bond wafer and the base wafer after bonding is located at within a range of 0&#xb1;30&#xb0; or 180&#xb1;30&#xb0; from a position at which separation of the bond wafer begins in the step of separating the bond wafer. This method can inhibit the occurrence of large fault defect that may be generated on a surface of a thin film right after the separation, when a thin film such as an SOI layer is formed by the ion implantation separation method.

Method of producing bonded wafer

The present invention is a method for manufacturing an SOI wafer, including: implanting one or more gas ion selected from a hydrogen ion and a rare gas ion into a bond wafer composed of a semiconductor single crystal substrate from a surface of the bond wafer to form an ion-implanted layer; bonding the surface from which the ion is implanted into the bond wafer and a surface of a base wafer through an oxide film; and then delaminating the bond wafer at the ion-implanted layer by performing a delamination heat treatment with a heat treatment furnace to form the SOI wafer, wherein after the delamination heat treatment, a temperature of the heat treatment furnace is decreased to 250&#xb0; C. or less at temperature-decreasing rate of less than 3.0&#xb0; C/min, and then the SOI wafer and the bond wafer after delamination are taken out from the heat treatment furnace.

According to the present invention, there is provided a method for manufacturing an SOI wafer having the step of performing a first sacrificial oxidation treatment on the aforementioned bonded SOI wafer in which the delamination has been performed after a first RTA treatment has been performed thereon and then performing a second sacrificial oxidation treatment thereon after a second RTA treatment has been performed thereon, wherein the first and second RTA treatments are performed under a hydrogen gas containing atmosphere and at a temperature of 1100&#xb0; C. or more, wherein after a thermal oxide film has been formed on the aforementioned SOI layer front surface by performing only thermal oxidation by a batch type heat treating furnace at a temperature of 900&#xb0; C. or more and 1000&#xb0; C. or less in the first and second sacrificial oxidation treatments, a treatment for removing the thermal oxide film is performed.

Method for manufacturing a bonded SOI wafer

A method for manufacturing a bonded wafer includes: an ion implantation step of using a batch type ion implanter; a bonding step of bonding an ion implanted surface of a bond wafer to a surface of a base wafer directly or through an insulator film; and a delamination step of delaminating the bond wafer at an ion implanted layer, thereby manufacturing a bonded wafer having a thin film on the base wafer, wherein the ion implantation into the bond wafer carried out at the ion implantation step is divided into a plurality of processes, the bond wafer is rotated on its own axis a predetermined rotation angle after each ion implantation, and the next ion implantation is carried out at an arrangement position obtained by the rotation.

Method for manufacturing bonded wafer and bonded SOI wafer

A method for calculating a warpage of a bonded SOI wafer includes: assuming that the epitaxial growth SOI wafer is a silicon single crystal wafer having the same dopant concentration as dopant concentration of the bond wafer; calculating a warpage A that occurs at the time of performing the epitaxial growth relative to the assumed silicon single crystal wafer; calculating a warpage B caused due to a thickness of the BOX layer of the epitaxial growth SOI wafer; determining a measured value of a warpage of the base wafer before bonding as a warpage C; and calculating a sum of the warpages (A+B+C) as the warpage of the bonded SOI wafer.

Method for calculating warpage of bonded SOI wafer and method for manufacturing bonded SOI wafer

A method for manufacturing an SOI wafer includes performing a flattening heat treatment on an SOI wafer under an atmosphere containing an argon gas, in which conditions of SOI wafer preparation are set so that a thickness of an SOI layer of the SOI wafer to be subjected to the flattening heat treatment is 1.4 or more times thicker than that of a BOX layer, and the thickness of the SOI layer is reduced to less than a thickness 1.4 times the thickness of the BOX layer by performing a sacrificial oxidation treatment on the SOI layer of the SOI wafer after the flattening heat treatment.

A method for checking an ion implantation condition when ions are implanted over an entirety of one surface of a semiconductor wafer having an insulator film on the one surface, the method including checking whether the ions are implanted over the entirety of the one surface of the semiconductor wafer by directly or indirectly observing light emitted when the one surface of the semiconductor wafer is irradiated with an ion beam of the implanted ions throughout the ion implantation.

Method for checking ion implantation condition and method for manufacturing semiconductor wafer

The present invention is directed to a method for manufacturing an SOI wafer, the method by which treatment that removes the outer periphery of a buried oxide film to obtain a structure in which a peripheral end of an SOI layer of an SOI wafer is located outside a peripheral end of the buried oxide film, and, after heat treatment is performed on the SOI wafer in a reducing atmosphere containing hydrogen or an atmosphere containing hydrogen chloride gas, an epitaxial layer is formed on a surface of the SOI layer. As a result, there is provided a method that can manufacture an SOI wafer having a desired SOI layer thickness by performing epitaxial growth without allowing a valley-shaped step to be generated in an SOI wafer with no silicon oxide film in a terrace portion, the SOI wafer fabricated by an ion implantation delamination method.

The present invention provides a method for manufacturing an SOI wafer wherein an HCl gas is mixed in a reactive gas at a step of forming a silicon epitaxial layer on an entire surface of an SOI layer of the SOI wafer having an oxide film on a terrace portion. As a result, it is possible to provide the method for manufacturing an SOI wafer that can easily grow the silicon epitaxial layer on the SOI layer of the SOI wafer having the oxide film on the terrace portion, suppress warpage of the SOI wafer to be manufactured, reduce generation of particles even at subsequent steps, e.g., device manufacture, and decrease a cost for manufacturing such an SOI wafer.

The invention is a method for forming a silicon oxide film of an SOI wafer, the method by which at least thermal oxidation treatment is performed (a process (A)) on an SOI wafer having an oxide film on the back surface and, after the thermal oxidation treatment, heat treatment is additionally performed (a process (B)) in a non-oxidizing atmosphere at a temperature higher than the temperature at which the thermal oxidation treatment was performed, whereby a silicon oxide film is formed on the front surface of an SOI layer. This provides a method for forming a silicon oxide film of an SOI wafer, the method that can prevent an SOI wafer from being warped after thermal oxidation treatment even when an SOI wafer having a thick oxide film on the back surface is used and a silicon oxide film for forming a device is formed by thermal oxidation on the front surface on the SOI layer side, and can reduce exposure failure and adsorption failure caused by warpage of the SOI wafer and enhance yields of device fabrication.

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Annaka, Japan

Isao Yokokawa