Chemische Fabrik Stockhausen Gmbh

Stockhausen Gmbh & Co Kg

Cerestar Holding B.v.

Rohm and Haas Company

Starchem, Inc.

Synthomer Chemie Gmbh

Frank Krause

Helmut Klimmek

Dolf Stockhausen

Klaus Heidel

Rudolf Beck

Udo Schoenkaes

Peter Hofmann

Wulf Ruback

Reinhard Kniewske

Gerd Jonas

Helmut Koch

Matthias Berghahn

Knut Moller

Gunter Rinck

Klaus Pfl&uuml;ger

Sigismund Fullert

The invention relates to an absorbent insert for foodstuff packagings, the liquid-absorbing component of which is a superabsorbent polymer which, in a hitherto unrivaled fashion, persistently absorbs and retains large quantities of liquid even under high pressure load, protects the foodstuffs from bacterial decay, and prevents contamination of the packaging goods by migrating soluble constituents of the polymer. This combination of properties of the superabsorbers used is expressed by the Q quotient of retention according to the tea bag test&plus;absorption against pressure (AAP) 0.3, divided by the amount of solubles (LA), which quotient is at least 20. Superabsorbers having such properties are obtained by using special combinations of crosslinkers. Furthermore, the invention relates to a process for producing said absorbent inserts and their use in foodstuff packagings, as ice substitute, and as leak-proofing means in transport packagings.

Absorbent inserts, method of producing them and their use

Interpolymers of unsaturated carboxylic acids and unsaturated sulfur acids

The present invention relates to water-soluble, acid-groups-containing graft copolymers which are at least partially biodegradable and are based on sugars and monoethylenically unsaturated carboxylic acids, sulfonic acids and/or phosphonic acids or the salts of said acids as well as optional further monomers. The present invention further relates to a process for producing the graft copolymers at temperatures of up to 200.degree. C. by means of radical polymerization initiators, in that a total mixture of 5-60%-wt. mono-, di- and oligosaccharides, the derivatives thereof or the mixtures thereof, and 95-40%-wt. of a monomer mixture comprising at least one monoethylenically unsaturated carboxylic acid, at least one monoethylenically unsaturated sulfonic acid, one monoethylenically unsaturated sulfuric acid ester and/or vinylphosphonic acid or the salts of said acids with monovalent cations, as well as optional further monomers is polymerized. The present invention further relates to the use of the graft copolymers in aqueous systems, for binding multivalent metal ions, inhibiting the water hardness, as additive in detergents and cleaning agents, as textile auxiliary, dispersing agent, in particular for pigments, and as auxiliary agent in the production of paper and leather.

Graft copolymers of unsaturated monomers and sugars, a process for the

The present invention relates to water-soluble, acid-groups-containing graft copolymers which are at least partially biodegradable and are based on sugars and monoethylenically unsaturated carboxylic acids, sulfonic acids and/or phosphonic acids or the salts of said acids as well as optional further monomers. The present invention further relates to a process for producing the graft copolymers at temperatures of up to 200.degree. C. by means of-radical polymerization initiators, in that a total mixture of 5-60%-wt. mono-, di- and oligosaccharides, the derivatives thereof or the mixtures thereof, and 95-40%-wt. of a monomer mixture comprising at least one monoethylenically unsaturated carboxylic acid, at least one monoethylenically unsaturated sulfonic acid, one monoethylenically unsaturated sulfuric acid ester and/or vinylphosphonic acid or the salts of said acids with monovalent cations, as well as optional further monomers is polymerized. The present invention further relates to the use of the graft copolymers in aqueous systems, for binding multivalent metal ions, inhibiting the water hardness, as additive in detergents and cleaning agents, as textile auxiliary, dispersing agent, in particular for pigments, and as auxiliary agent in the production of paper and leather.

Dispersions of graft copolymers of unsaturated monomers and sugars

Biodegradable copolymers, methods of producing them and their use

Graft copolymers of unsaturated monomers and polyhydroxy compounds, a

Water-softening formulations which comprise:

Water-softening compositions

The preparation of terpolymers by free radical polymerization of an unsaturated dicarboxylic acid with an unsaturated monocarxylic acid and a further saturated monomer which contains no free carboxyl groups, in an aqueous medium, is carried out, according to the invention, in the presence of surfactant compounds.

Process for the preparation of dicarboxylic acid terpolymers for

The present invention relates to detergent formulations which contain

Detergent formulations free of phosphates, zeolites and crystalline

Finely divided polysaccharide graft polymers having a high absorption capacity for urine and water are prepared by semi-continuous reverse-phase suspension polymerization, in which an aqueous solution of an unsaturated carboxylic acid and an initiator is metered continuously into a suspension of a polysaccharide in an organic solvent and the polymer obtained is subsequently partial dehydrated and the crosslinked.

Process for the preparation of finely divided, water-swellable

A process is described for the production of an aqueous polymer dispersion by polymerization of ethylenically unsaturated compounds by means of free-radical initiators in the presence of starch and/or starch derivatives and optional further conventional adjuvants, and which the dispersions are coagulate-free, have a low viscosity, and a small particle size, said process comprising polymerizing an ethylenically unsaturated diene monomer or mixture of monomers consisting of

Process of producing aqueous polymer dispersions

The present invention relates to an aqueous acrylate polymer dispersion having a total solids content of 30 to 60% by weight polymerizing one or more acrylate monomers optionally together with other olefinically unsaturated monomer(s) in the presence of dextrin at least 70% of which has a molecular weight in the range of 1000 to 25000 and not more than 10% has a molecular weight above 25000.

Growing community of inventors

Kleve, Germany

Frank Krause