Tokyo Electron Limited

Motorola Corporation

International Business Machines Corporation

David L O'Meara

Cory Wajda

Anthony Dip

Angelique Denise Raley

Kandabara N Tapily

Sufi Zafar

Gerrit J Leusink

Andrew W Metz

Eric Chih-Fang Liu

Yun Han

Xinghua Sun

Kristen Scheer

Bich-Yen Nguyen

Ramachandran Muralidhar

Jeffrey Smith

Robert Daniel Clark

Akiteru Ko

Alessandro Cesare Callegari

Philip J Tobin

Kai-Hung Yu

Aelan Mosden

Nicholas Joy

Yeong-Jyh Tom Lii

Masanobu Igeta

Yen-Tien Lu

Sucharita Madhukar

Victor S Wang

Evgeni Petrovich Gousev

Richard Anthony Conti

Anthony I Chou

Michael Alan Sadd

Rama I Hegde

Pao-Hwa Chou

Bruce E White

Richard Farrell

Stanley Michael Filipiak

Michael P Woo

Gert J Leusink

Hsing-Huang Tseng

Soo Doo Chae

Terry Grant Sparks

Katie Lutker-Lee

Jodi Grzeskowiak

Craig S Lage

Shan Hu

Henan Zhang

Shihsheng Chang

Andrew G Nagy

Takahiro Hakamata

Mousumi Bhat

T P Ong

Larry E Frisa

Gyanaranjan Pattanaik

Carol M Gelatos

Paul J Higgins

Fred Buehrer

Daniel Craig Burdett

Stephen H Cabral

John William Kostenko

Michael Toeller

Toshihara Furukawa

Anton J deVillers

Paul Charles Jamison

Chitra K Subramanian

Kaushik Arun Kumar

Srikanth Balaji Samavedam

Hideaki Yamasaki

William James Taylor, Jr

Toshio Hasegawa

Nihar Mohanty

Lior Huli

Hoyoung Kang

Kunihiro Tada

Tsuyoshi Takahashi

Kiyohito Ito

Bo Jiang

Percy V Gilbert

Steven Consiglio

Shingo Maku

Steven Grzeskowiak

Wan Jae Park

Kristen C Smith

Eric Chih Fang Liu

David Rosenthal

Cheryl Alix

Toshihara Eurakawa

YoungJong Lee

A method of forming a semiconductor device includes forming, over a hardmask layer and an underlying layer of a substrate, a pattern of first trenches between adjacent template lines, each of the first trenches exposing a portion of the hardmask layer, and each of the template lines including a mandrel and spacers on sidewalls of the mandrel; forming a pattern of first blocks over the pattern of the first trenches and the template lines, the first blocks dividing the first trenches to form a pattern of first stencil trenches; transferring the pattern of first stencil trenches to the hardmask layer to form a pattern of first hardmask trenches, each of the first hardmask trenches exposing a portion of the underlying layer; forming a first fill layer filling the first hardmask trenches and exposing the mandrels; selectively removing the mandrels to form second trenches, each of the second trenches exposing a portion of the hardmask layer; and forming a conformal liner in the second trenches and over a surface of the spacers, a surface of the first blocks, and a surface of the first fill layer to form third trenches.

Double patterning method of patterning a substrate

A method includes providing a substrate including metal gate stacks and source/drain contact regions in alternating arrangement along a surface of the substrate with a dielectric spacer separating each source/drain contact region from adjacent metal gate stacks. Each source/drain region is recessed within an opening between adjacent metal gate stacks such that source/drain contact regions provide a bottom of the recess and dielectric spacers provide sidewalls. The etch stop layer is formed on the substrate such that it conformally covers the metal gate stacks, the sidewalls and the bottom of each recess, and a sacrificial layer is formed over each of the metal gate stacks and on at least a portion of each sidewall. The etch stop layer is removed from the bottom of each recess to expose the source/drain contact, and the sacrificial layer is then removed from the metal gate stacks and the sidewalls of each recess.

Sacrificial capping layer for gate protection

Methods are provided for planarizing a patterned substrate in a spatial atomic layer processing system comprising a rotating platen. The patterned substrate may generally include features having higher regions and lower regions. To planarize the patterned substrate, or reduce a height differential between the higher and lower regions, a selective atomic layer etching (ALE) process is disclosed to preferentially form a modified layer on the higher regions of the features by exposing a surface of the patterned substrate to a precursor gas while the rotating platen spins at a high rotational speed. By preferentially forming the modified layer on the higher regions of the features, and subsequently removing the modified layer, the selective ALE process described herein preferentially etches the higher regions of the features to lessen the height differential between the higher and lower regions until a desired planarization of the features is achieved.

Systems and methods for improving planarity using selective atomic layer etching (ALE)

Methods are disclosed that provide improved via profile control by forming atomic layer deposition (ALD) liners to protect side walls of vias during subsequent etch processes. ALD liners can be used for BEOL etch processes as well as for full self-aligned via (FSAV) processes and/or other processes. For one embodiment, ALD liners are used as protection or sacrificial layers for vias to reduce damage during multilayer via or trench etch processes. The ALD liners can also be deposited at different points within process flows, for example, before or after removal of organic planarization layers. The use of ALD liners facilitates shrinking of via critical dimensions (CDs) while still controlling via profiles for various process applications including dual Damascene processes and FSAV processes. In addition, the use of ALD liners improves overall CD control for via or hole formation as well as device yield and reliability.

ALD (atomic layer deposition) liner for via profile control and related applications

Improved process flows and methods are provided herein for forming a passivation layer on sidewall surfaces of openings formed in an amorphous carbon layer (ACL) to avoid bowing during an ACL etch process. More specifically, improved process flows and methods are provided to form a silicon-containing passivation layer on sidewall surfaces of the openings created within the ACL without utilizing atomic layer deposition (ALD) techniques or converting the silicon-containing passivation layer to an oxide or a nitride. As such, the improved process flows and methods disclosed herein may be used to protect the sidewall surfaces of the ACL and prevent bowing during the ACL etch process, while also reducing processing time and improving throughput.

Non-atomic layer deposition (ALD) method of forming sidewall passivation layer during high aspect ratio carbon layer etch

Improved process flows and methods are provided herein for trimming structures formed on a patterned substrate. In the disclosed process flows and methods, a self-aligned multiple patterning (SAMP) process is utilized for patterning structures, such as mandrels, on a substrate. After the structures are patterned, an atomic layer deposition (ALD) process is used to form a spacer layer on the patterned structures. In the SAMP process disclosed herein, a critical dimension (CD) of the patterned structures is trimmed concurrently with, and as a result of, the formation of the spacer layer by controlling various ALD process parameters and conditions. By trimming the patterned structures in situ of the ALD chamber used to form the spacer layer on the patterned structures, the improved process flows and methods described herein provide a CD trim method that does not adversely affect the pattern profile or process throughput.

Method for critical dimension (CD) trim of an organic pattern used for multi-patterning purposes

A method for filling recessed features with a low-resistivity metal. The method includes providing a patterned substrate containing a recessed feature formed in a first layer and a second layer that is exposed in the recessed feature, and pre-treating the substrate with a surface modifier that increases metal deposition selectivity on the second layer relative to on the first layer, depositing a metal layer on the substrate by vapor phase deposition, where the metal layer is preferentially deposited on the second layer in the recessed feature, and removing metal nuclei deposited on the first layer, including on a field area and on sidewalls of the first layer in the recessed feature, to selectively form the metal layer on the second layer in the recessed feature. The steps of pre-treating, depositing and removing may be repeated at least once to increase a thickness of the metal layer in the recessed feature.

Method for filling recessed features in semiconductor devices with a low-resistivity metal

A method of processing a substrate includes: providing structures on a surface of a substrate; depositing a self-assembled monolayer (SAM) over the structures and the substrate, the SAM being reactive to a predetermined wavelength of radiation; determining a first pattern of radiation exposure, the first pattern of radiation exposure having a spatially variable radiation intensity across the surface of the substrate and the structures; exposing the SAM to radiation according to the first pattern of radiation exposure, the SAM being configured to react with the radiation; developing the SAM with a predetermined removal fluid to remove portions of the SAM that are not protected from the predetermined fluid; and depositing a spacer material on the substrate and the structures, the spacer material being deposited at varying thicknesses based on an amount of the SAM remaining on the surface of the substrate and the structures.

Method for globally adjusting spacer critical dimension using photo-active self-assembled monolayer

In one embodiment, a method includes providing a substrate comprising a source/drain contact region and a dummy gate, forming a first etch stop layer aligned to the source/drain contact region, where the first etch stop layer does not cover the dummy gate. The method may include forming a second etch stop layer over the first etch stop layer, the second etch stop layer covering the first etch stop layer and the dummy gate. The method may include converting the dummy gate to a metal gate. The method may include removing the second etch stop layer using a plasma etching process. The method may include removing the first etch stop layer.

Localized etch stop layer

A method of forming a device includes depositing a first etch mask layer over a mandrel formed using a lithography process. The method includes depositing a second etch mask layer over the first etch mask layer. The method includes, using a first anisotropic etching process, etching the first etch mask layer and the second etch mask layer to form an etch mask including the first etch mask layer and the second etch mask layer. The method includes removing the mandrel to expose an underlying surface of the layer to be patterned. The method includes, using the etch mask, forming a feature by performing a second anisotropic etching process to pattern the layer to be patterned, where during the first anisotropic etching process, the first etch mask layer etches at a first rate and the second etch mask layer etches at a second rate, and where the first rate is different from the second rate.

Multiple patterning processes

A method of patterning a substrate includes receiving a substrate having microfabricated structures, including mandrels; executing a deposition process that deposits a first material on the mandrels, the deposition process including cyclically moving the substrate through a set of deposition modules. The substrate is moved through the set of deposition modules so that the first material is deposited at a first thickness at top portions of the mandrels and at a second thickness at bottom portions of mandrels, the first thickness being greater than the second thickness. The method includes executing a spacer deposition process that conformally deposits a second material on the substrate; executing a spacer open etch that removes depositions of the second material from over a top surface of the mandrels; removing the first material and the mandrels from the substrate, leaving sidewall spacers; and transferring a pattern defined by the sidewall spacers into an underlying layer.

Deposition process

An atomic layer deposition (ALD) technique is used to deposit one or more layers on hard mask layers and the sidewalls of low-K dielectric trench as part of the trench etch process. The ALD layer(s) can prevent the hard mask from being eroded during various hard mask open processes. Further, the ALD layer(s) may be utilized to prevent the low-K dielectric sidewall from being laterally etched during the low-K dielectric trench etch. Hence, better control of the trench profile and better critical dimension control may be provided.

Atomic layer deposition for low-K trench protection during etch

Growing community of inventors

Albany, NY, United States of America

David L O'Meara