General Electric Company

David G Hawron

Roy Ray Odle

Thomas Link Guggenheim

Deborah Ann Haitko

Joseph A King, Jr

Sunita Singh Baghel

Brent A Dellacoletta

James P Barren

Ronald A Greenberg

Margaret Louise Blohm

Dean S Matsumoto

A process for making bis(ether anhydrides) employs alkylamines having low melting temperatures thus allowing for novel intermediate process steps for preparing bis(ether anhydrides). The alkylamines have alkyl groups which contain at least three carbon atoms and have boiling temperatures in the range of 48 to 250.degree. C. at atmospheric pressure. As a result of using these amines, liquid alkylamines now can be employed in the imidization process step. The N-alkyl nitrophthalimides prepared from the recovered imidization product according to this invention can now be purified using liquid/liquid extraction or vacuum distillation. The alkyl nitrophthalimides prepared according to this invention provide for displacement reactions which now can be run at a high solids level. Likewise, the exchange reaction can be run at a higher solids level, and thus achieves an efficiency level which is higher than conventional processes.

Process for preparing bis (ether anhydrides) using alkylamine derived

Process for preparing BIS(ether anhydrides) using alkylamine derived

A process for making bis(ether anhydrides) employs alkylamines having low melting temperatures thus allowing for novel intermediate process steps for preparing bis(ether anhydrides). The alkylamines have alkyl groups which contain at least three carbon atoms and have boiling temperatures in the range of 48.degree. to 250.degree. C. at atmospheric pressure. As a result of using these amines, liquid alkylamines now can be employed in the imidization process step. The N-alkyl nitrophthalimides prepared from the recovered imidization product according to this invention can now be purified using liquid/liquid extraction or vacuum distillation. The alkyl nitrophthalimides prepared according to this invention provide for displacement reactions which now can be run at a high solids level. Likewise, the exchange reaction can be run at a higher solids level, and thus achieves an efficiency level which is higher than conventional processes.

Process for preparing bis(ether anhydrides) using alkylamine derived

Thermoplastic resin sheets, particularly in the form of fiber-reinforced composites, have adherent cap layers, at least one of which comprises an intumescent polydiorganosiloxane-containing barrier material which forms upon ignition a thermally stable foamed char layer. Such articles have improved fire resistance in comparison with similar articles having no cap layer or non-intumescent cap layers.

Resinous construction material having fire-resistant intumescent cap

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Clifton Park, NY, United States of America

David G Hawron