Taiwan Semiconductor Manufacturing Comp. Ltd.

Chung-Chieh Liu

Chwen-Ming Liu

Jiann-Jong Wang

Been-Hon Lin

Bing-Huei Peng

A chemical vapor deposition (CVD) method for forming a doped silicate glass dielectric layer within a microelectronics fabrication. There is first positioned within a reactor chamber a substrate employed within a microelectronics fabrication. There is then stabilized within the reactor chamber with respect to the substrate a first flow of a silicon source material absent a flow of a dopant source material. There is then deposited upon the substrate within the reactor chamber a doped silicate glass dielectric layer through a chemical vapor deposition (CVD) method. The doped silicate glass dielectric layer is formed employing a second flow of the silicon source material, a flow of an oxidant source material and the flow of the dopant source material. There may subsequently be formed through the doped silicate glass dielectric layer an anisotropically patterned via through an anisotropic patterning method. The anisotropically patterned via may then be isotropically etched to form an isotropically etched anisotropically patterned via without void formation within the sidewalls of the isotropically etched anisotropically patterned via.

Pre deposition stabilization method for forming a void free

A method for forming an anti-reflective-coating(ARC) layer is described. This ARC layer performs not only in its capacity to reduce reflections from its subjacent metal layer during the metal patterning photoresist exposure, but also serves as an effective etch inhibitor during subsequent via etching. Of particular importance is the ability provided by this ARC layer to sustain its etch resistance during considerable over etching such as is required when vias of different depths are to be opened. The ARC layer differs from the conventional titanium nitride ARC layer in that it has a base layer of titanium below the titanium nitride portion. It is this titanium layer and an optional intermediate Ti rich layer that sustains the over etch. Additionally, the titanium forms an improved bonding with the metal beneath providing reduced via contact resistance and greater via stability and consistency.

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Hsinchu, Taiwan

Chung-Chieh Liu