Idemitsu Kosan Company, Limited

Aki Yamada

Yasuhiro Ishikawa

Koichi Suga

Yusuke Aoki

Yumi Nakayama

Provided is a polycarbonate-based resin having a ratio of an amine terminal to all terminal groups of 1.0 mol % or more.

Polycarbonate-based resin, production method therefor, and polycarbonate-based resin composition

Provided is a polycarbonate-based resin composition containing: a polycarbonate-polyorganosiloxane copolymer (A-1) which contains a specific repeating unit and in which a polyorganosiloxane block has an average chain length of 20 or more and less than 60; a polycarbonate-polyorganosiloxane copolymer (A-2) which contains a specific repeating unit and in which a polyorganosiloxane block has an average chain length of 60 or more and less than 500; and a polycarbonate-based resin (A-3) except the polycarbonate-polyorganosiloxane copolymer (A-1) and the polycarbonate-polyorganosiloxane copolymer (A-2), wherein the ratio of the polycarbonate-based resin (A-3) to the total weight of the polycarbonate-polyorganosiloxane copolymer (A-1), the polycarbonate-polyorganosiloxane copolymer (A-2), and the polycarbonate-based resin (A-3) is 10 mass % or more.

Polycarbonate resin composition

Provided is a polycarbonate-based resin composition, including: 10 to 90 mass % of a polycarbonate-polyorganosiloxane copolymer (E-1); and 10 to 90 mass % of an aromatic polycarbonate resin (E-2) except the polycarbonate-polyorganosiloxane copolymer (E-1), in which the molecular weight distribution of the polyorganosiloxane block of the polycarbonate-polyorganosiloxane copolymer is controlled within a specific region.

Polycarbonate resin composition and molded body of same

Provided is a polycarbonate-based resin composition containing a polycarbonate-based resin containing a polycarbonate-polyorganosiloxane copolymer, and 0.01 to 1.0 part by mass of a UV absorber with respect to 100 parts by mass of the polycarbonate-based resin, in which the molecular weight distribution of a polyorganosiloxane block in the polycarbonate-polyorganosiloxane copolymer is controlled within a specific region.

Provided is a polycarbonate-based resin composition, including 0.001 part by mass to 1 part by mass of a flame retardant (C) with respect to 100 parts by mass of a polycarbonate-based resin containing a polycarbonate-polyorganosiloxane copolymer (E-1), in which: the polycarbonate-polyorganosiloxane copolymer (E-1) has a polycarbonate block (A) formed of a repeating unit represented by the following general formula (I) and a polyorganosiloxane block (B) containing a repeating unit represented by the following general formula (II); and in a differential molecular weight distribution curve obtained from measurement of the polyorganosiloxane block (B) by gel permeation chromatography using the polystyrene calibration curve, the curve having the axis of abscissa indicating a logarithmic value log(M) of a molecular weight M and the axis of ordinate indicating dw/d log(M) obtained by differentiating a concentration fraction w with respect to the logarithmic value log(M) of the molecular weight, (1) a dw/d log(M) value becomes maximum in the range of 3.4&#x2264;log(M)&#x2264;4.0, and (2) a ratio of a value obtained by integrating the dw/d log(M) value over the range of 4.00&#x2264;log(M)&#x2264;4.50 to a value obtained by integrating the dw/d log(M) value over the entire range of the log(M) in the differential molecular weight distribution curve is 6 to 40%.

Polycarbonate resin composition and molded product thereof

Provided is a polycarbonate-based resin composition containing a polycarbonate-based resin containing a predetermined polycarbonate-polyorganosiloxane copolymer, and 0.5 to 5 parts by mass of a white pigment with respect to 100 parts by mass of the polycarbonate-based resin, in which the molecular weight distribution of a polyorganosiloxane block in the polycarbonate-polyorganosiloxane copolymer is controlled within a specific region.

Polycarbonate-based resin composition and molded article thereof

Provided is a polycarbonate-polyorganosiloxane copolymer, including a specific polycarbonate block unit (A) and a specific polyorganosiloxane block unit (B), in which in a differential molecular weight distribution curve obtained from measurement of the polyorganosiloxane block unit (B) by gel permeation chromatography using the polystyrene calibration curve, the curve having an axis of abscissa indicating a logarithmic value log(M) of a molecular weight M and an axis of ordinate indicating dw/d log(M) obtained by differentiating a concentration fraction w with respect to the logarithmic value log(M) of the molecular weight, (1) a dw/d log(M) value becomes maximum in a range of 3.4&#x2266;log(M)&#x2266;4.0, and (2) in the differential molecular weight distribution curve, a ratio of a value obtained by integrating the dw/d log(M) value over a range of 4.0&#x2266;Log(M)&#x2266;4.5 to a value obtained by integrating the dw/d log(M) value over the entire range of the log(M) is 6% or more and 40% or less.

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Sodegaura, Japan

Aki Yamada