The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 19, 2016

Filed:

Jul. 01, 2014
Applicant:

Basf SE, Ludwigshafen OT, DE;

Inventors:

Gabriele Gralla, Mannheim, DE;

Gunnar Heydrich, Limburgerhof, DE;

Klaus Ebel, Lampertheim, DE;

Wolfgang Krause, Bruehl-Rohrhof, DE;

Assignee:

BASF SE, Ludwigshafen, DE;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 39/16 (2005.12); C07C 39/12 (2005.12); C07C 45/74 (2005.12); C07C 37/07 (2005.12); C07C 37/20 (2005.12); C07C 37/62 (2005.12);
U.S. Cl.
CPC ...
C07C 45/74 (2012.12); C07C 37/07 (2012.12); C07C 37/20 (2012.12); C07C 37/62 (2012.12);
Abstract

The present invention relates to a process for preparing 4,4'-[1-(trifluoromethyl)alkylidene]bis(2,6-diphenylphenols), in particular for preparing 4,4′-[1-(trifluoromethyl)ethylidene]bis(2,6-diphenylphenol), which comprises the self-condensation of cyclohexanone in the presence of a basic catalyst to form tricyclic condensation products, dehydrogenation of the resulting tricyclic condensation products in the presence of a supported transition metal catalyst in the condensed phase to form 2,6-diphenylphenol and reaction of the 2,6-diphenylphenol with a trifluoromethyl ketone. The invention further provides an improved process for preparing 2,6-diphenylphenol by aldol self-condensation of cyclohexanone.


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