The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 05, 2018

Filed:

Aug. 18, 2014
Applicant:

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

Linfeng Chen, Missouri City, TX (US);

Robert J. Jorgensen, Fort Bragg, CA (US);

Stephanie M. Whited, South Charleston, WV (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 2/38 (2006.01); C08F 4/12 (2006.01); C08F 26/00 (2006.01); C08F 210/16 (2006.01);
U.S. Cl.
CPC ...
C08F 210/16 (2013.01);
Abstract

The instant invention provides a method for polymerizing one or more ethylene-based polymers. The method for polymerizing one or more ethylene-based polymers according to the present invention comprises the following steps: (1) selecting ethylene and optionally one or more alpha-olefin comonomers; (2) selecting one or more catalyst systems comprising one or more procatalysts comprising Ti, one or more cocatalysts comprising Al, and one or more self-limiting agents (SLA); wherein the ratio of SLA to Ti is from 5:1 to 40:1 and the ratio of Al to SLA is from 2:1 to 40:1; (3) polymerizing said ethylene and optionally one or more alpha-olefin comonomers in the presence of said one or more catalyst systems via a slurry polymerization process or gas-phase polymerization process in one or more reactors; (4) thereby producing one or more ethylene; wherein said catalyst system has a loss of least 85% of catalyst productivity when the temperature is increased from 85 to 115 C.


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