The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 22, 2018

Filed:

Jun. 22, 2015
Applicant:

Arkema France, Colombes, FR;

Inventors:

Anne Moreliere, Longeville-les-St-Avold, FR;

Gilles Frimour, Dalstein, FR;

Jean-Michel Paul, Metz, FR;

Stephane Denis, Leyviller, FR;

Assignee:

ARKEMA FRANCE, Colombes, FR;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 67/48 (2006.01); C07C 67/08 (2006.01); C07C 67/54 (2006.01);
U.S. Cl.
CPC ...
C07C 67/08 (2013.01); C07C 67/54 (2013.01);
Abstract

The present invention relates to a method for producing a C-Calkyl (meth)acrylate, by direct esterification of (meth)acrylic acid by the corresponding alcohol, the reaction water being removed in the form of an azeotrope with the esterification alcohol from a distillation column mounted over the esterification reactor comprising a cationic resin as a catalyst. Said method is characterized in that the molar ratio of alcohol to acid at the inlet of the reactor is between 1.4 and 3, and in that the crude reaction mixture circulates in a recirculation loop joining the reactor and the water removal column, at a recirculation rate of between 6 and 25, expressed by the mass ratio between the flow fed into the loop and the flow sent to a purification treatment.


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