The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 08, 2018

Filed:

Sep. 03, 2014
Applicant:

Uchicago Argonne, Llc, Chicago, IL (US);

Inventors:

Lu Zhang, Lisle, IL (US);

Jinhua Huang, Willowbrook, IL (US);

Anthony Burrell, Naperville, IL (US);

Assignee:

UCHICAGO ARGONNE, LLC, Argonne, IL (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
H01M 8/18 (2006.01); H01M 8/20 (2006.01); H01M 4/90 (2006.01);
U.S. Cl.
CPC ...
H01M 8/188 (2013.01); H01M 8/20 (2013.01); H01M 4/9008 (2013.01); H01M 2300/0028 (2013.01); Y02E 60/528 (2013.01);
Abstract

The present invention provides a non-aqueous redox flow battery comprising a negative electrode immersed in a non-aqueous liquid negative electrolyte, a positive electrode immersed in a non-aqueous liquid positive electrolyte, and a cation-permeable separator (e.g., a porous membrane, film, sheet, or panel) between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise an electrolyte salt (e.g., a lithium or sodium salt), a transition-metal free redox reactant, and optionally an electrochemically stable organic solvent. Each redox reactant is selected from an organic compound comprising a conjugated unsaturated moiety, a boron cluster compound, and a combination thereof. The organic redox reactant of the positive electrolyte comprises a tetrafluorohydroquinone ether compound or a tetrafluorocatechol ether compound.


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