The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 01, 2018

Filed:

Aug. 18, 2014
Applicant:

International Business Machines Corporation, Armonk, NY (US);

Inventors:

Dylan J. Boday, Tucson, AZ (US);

Jeannette M. Garcia, San Jose, CA (US);

James L. Hedrick, Pleasanton, CA (US);

Alshakim Nelson, San Carlos, CA (US);

Rudy J. Wojtecki, San Jose, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 12/08 (2006.01); B29C 67/00 (2017.01); B33Y 10/00 (2015.01); B33Y 70/00 (2015.01); B29K 61/20 (2006.01);
U.S. Cl.
CPC ...
C08G 12/08 (2013.01); B29C 67/0055 (2013.01); B29K 2061/20 (2013.01); B33Y 10/00 (2014.12); B33Y 70/00 (2014.12);
Abstract

This application describes methods of forming an object. The methods described include flowing a polyhemiaminal (PHA), polyhexhydrotriazine (PHT), or polyoctatriazacane (POTA) precursor mixture to a nozzle of a 3D printer, heating the PHA, PHT, or POTA precursor to a temperature of at least 50° C., dispensing the PHA, PHT, or POTA precursor in a pattern; and, hardening the PHA, PHT, or POTA precursor into a polymer. The PHA and PHT polymers are formed by reacting a primary diamine with a formaldehyde-type reagent. The POTA polymer is formed by reacting a primary diamine with a formaldehyde-type reagent and formic acid. The objects formed using the methods described herein may be made of a single polymer, a single polymer type using multiple diamine monomers, or a mixture of PHA, PHT, and/or POTA polymers with different desired physical properties.


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