The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 17, 2018

Filed:

Sep. 02, 2014
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Chuansheng Bai, Phillipsburg, NJ (US);

Jean W. Beeckman, Columbia, MD (US);

Adrienne J. Thornburg, Columbus, OH (US);

Natalie A. Fassbender, Nazareth, PA (US);

Sabato Miseo, Pittstown, NJ (US);

Stuart L. Soled, Pittstown, NJ (US);

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 29/149 (2006.01); B01J 23/46 (2006.01); B01J 37/02 (2006.01); B01J 37/08 (2006.01); B01J 37/10 (2006.01); B01J 37/18 (2006.01); B01J 23/42 (2006.01); B01J 23/44 (2006.01); B01J 31/12 (2006.01); B01J 35/00 (2006.01); B01J 35/10 (2006.01); C07C 67/303 (2006.01); B01J 21/08 (2006.01); B01J 27/24 (2006.01);
U.S. Cl.
CPC ...
B01J 23/462 (2013.01); B01J 23/42 (2013.01); B01J 23/44 (2013.01); B01J 23/464 (2013.01); B01J 31/123 (2013.01); B01J 35/002 (2013.01); B01J 35/1014 (2013.01); B01J 35/1019 (2013.01); B01J 35/1061 (2013.01); B01J 37/0203 (2013.01); B01J 37/0207 (2013.01); B01J 37/0209 (2013.01); B01J 37/0242 (2013.01); B01J 37/0244 (2013.01); B01J 37/08 (2013.01); B01J 37/10 (2013.01); B01J 37/18 (2013.01); C07C 29/149 (2013.01); C07C 67/303 (2013.01); B01J 21/08 (2013.01); B01J 27/24 (2013.01); B01J 2531/821 (2013.01); B01J 2540/62 (2013.01);
Abstract

A method of preparing a hydrogenation catalyst, for example, a phthalate hydrogenation catalyst, comprising contacting a silica support having a median pore size of at least about 10 nm with a silylating agent to form an at least partially coated silica support, calcining said coated silica support to form a treated silica support, and depositing a noble metal, preferably ruthenium, on the treated silica support, and optionally contacting the treated silica support with an optional chelating agent to form the hydrogenation catalyst; a hydrogenation catalyst prepared by that method; and a method of hydrogenating unsaturated hydrocarbons, such as phthalates, in which an unsaturated hydrocarbon is contacted with hydrogen gas in the presence of the hydrogenation catalyst of the invention.


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