The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 10, 2018

Filed:

Feb. 01, 2016
Applicant:

Battelle Memorial Institute, Pacific Northwest National Laboratories, Richland, WA (US);

Inventors:

Wei Liu, Richland, WA (US);

Xiaohong Shari Li, Richland, WA (US);

Assignee:

Battelle Memorial Institute, Richland, WA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 7/00 (2006.01); C01B 3/36 (2006.01); B01J 23/83 (2006.01); C01B 3/56 (2006.01); B01J 20/04 (2006.01); C01B 3/38 (2006.01); B01J 19/24 (2006.01); B01J 8/02 (2006.01); B01J 37/06 (2006.01); B01J 37/08 (2006.01); B01J 21/06 (2006.01); B01J 23/00 (2006.01); B01J 23/755 (2006.01); B01J 35/00 (2006.01); B01J 35/04 (2006.01); B01J 35/10 (2006.01); B01J 37/02 (2006.01);
U.S. Cl.
CPC ...
B01J 23/83 (2013.01); B01J 8/0242 (2013.01); B01J 19/2485 (2013.01); B01J 20/043 (2013.01); B01J 21/063 (2013.01); B01J 23/002 (2013.01); B01J 23/755 (2013.01); B01J 35/002 (2013.01); B01J 35/04 (2013.01); B01J 35/1014 (2013.01); B01J 35/1019 (2013.01); B01J 35/1038 (2013.01); B01J 37/0201 (2013.01); B01J 37/06 (2013.01); B01J 37/08 (2013.01); C01B 3/38 (2013.01); C01B 3/56 (2013.01); B01J 2208/00274 (2013.01); B01J 2208/00309 (2013.01); B01J 2208/025 (2013.01); B01J 2219/243 (2013.01); B01J 2219/2414 (2013.01); B01J 2219/2428 (2013.01); B01J 2219/2448 (2013.01); B01J 2523/00 (2013.01); C01B 2203/0233 (2013.01); C01B 2203/0283 (2013.01); C01B 2203/0425 (2013.01); C01B 2203/0475 (2013.01); C01B 2203/1023 (2013.01); C01B 2203/1041 (2013.01); C01B 2203/1058 (2013.01); C01B 2203/1076 (2013.01); C01B 2203/1247 (2013.01); Y02P 20/145 (2015.11); Y02P 20/52 (2015.11);
Abstract

A reactor and process for production of hydrogen gas from a carbon-containing fuel in a reaction that generates carbon dioxide is described. The carbon-containing fuel can be, for example, carbon monoxide, alcohols, oxygenates bio-oil, oil and hydrocarbons. In preferred embodiments, the reactor includes a monolithic structure form with an array of parallel flow channels. Methods of using the reactor are also described. In the reactor apparatus of the present invention, the catalytic reaction for hydrogen formation is conducted in conjunction with a carbonation reaction that removes carbon dioxide that is produced by the reactor. The carbonation reaction involves reaction of the carbon dioxide produced from the hydrogen formation reaction with metal oxide-based sorbents. The reactor apparatus can be periodically regenerated by regeneration of the sorbent. A carbon dioxide sorbent system comprising a solid sorbent and a eutectic, mixed alkali metal molten phase is also described.


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