The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 20, 2018

Filed:

Jan. 10, 2015
Applicant:

Zhejiang University, Hangzhou, CN;

Inventors:

Shaohong Xu, Hangzhou, CN;

Xiang Gao, Hangzhou, CN;

Yingwu Luo, Hangzhou, CN;

Assignee:

ZHEJIANG UNIVERSITY, Zhejiang, CN;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C08F 293/00 (2006.01); C08F 2/24 (2006.01); C08F 2/10 (2006.01);
U.S. Cl.
CPC ...
C08F 293/00 (2013.01); C08F 2/10 (2013.01); C08F 2/24 (2013.01);
Abstract

The present invention discloses a block copolymer comprising a block with glass transition temperature higher than 100° C. and a method for preparing the same. In the method, latex of a block copolymer is prepared by taking n-butyl acrylate as a soft block, random copolymer of styrene and γ-methyl-α-methylene-γ-butyrolactone as a hard block, utilizing emulsion polymerization system and reversible addition fragmentation chain transfer radical polymerization technology. The method utilizes an amphiphilic macromolecule reversible addition fragmentation chain transfer agent has dual function of both chain transfer agent and emulsifier, thus can achieve good control of monomer polymerization and avoid the use of traditional emulsifier; the reaction has no polymerization inhibition period, has fast reaction rate and high final conversion; colloidal particles can stably grow; product has a hard block with glass transition temperature up to 155° C., and thus has a good application prospect in the field of high heat resistance thermoplastic elastomer.


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