The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 20, 2018

Filed:

Jul. 08, 2015
Applicant:

Dow Global Technologies Llc, Midland, MI (US);

Inventors:

Adam Chojecki, Terneuzen, NL;

Davy Nieskens, Terneuzen, NL;

Thomas Davidian, Terneuzen, NL;

Peter E. Groenendijk, Hulst, NL;

Matthijs Ruitenbeek, Terneuzen, NL;

Barry B. Fish, Freeport, TX (US);

Max M. Tirtowidjojo, Freeport, TX (US);

Garmt R. Meima, Terneuzen, NL;

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 1/04 (2006.01); C07C 1/12 (2006.01); B01J 37/03 (2006.01); B01J 37/04 (2006.01); B01J 35/02 (2006.01); B01J 35/00 (2006.01); B01J 23/26 (2006.01); B01J 29/85 (2006.01); B01J 23/80 (2006.01);
U.S. Cl.
CPC ...
C07C 1/043 (2013.01); B01J 23/26 (2013.01); B01J 23/80 (2013.01); B01J 29/85 (2013.01); B01J 35/0006 (2013.01); B01J 35/026 (2013.01); B01J 37/031 (2013.01); B01J 37/04 (2013.01); C07C 1/12 (2013.01); C07C 2521/04 (2013.01); C07C 2523/06 (2013.01); C07C 2523/26 (2013.01); C07C 2523/72 (2013.01); C07C 2523/80 (2013.01); C07C 2529/85 (2013.01);
Abstract

A feedstream comprising hydrogen and a gas selected from carbon monoxide, carbon dioxide, or a combination thereof is converted to a product mixture containing a combination of saturated and unsaturated two carbon atom and three carbon atom hydrocarbons via contact with a mixed catalyst comprising a mixed metal oxide catalyst selected from a copper oxide, copper oxide/zinc oxide, copper oxide/alumina, copper oxide/zinc oxide/alumina catalyst, a zinc oxide/chromium oxide catalyst, or a combination thereof, in admixture with a molecular sieve catalyst having a CHA, AEI, AEL, AFI, BEA, or DDR framework type, or a combination of such molecular sieves. Exemplary molecular sieve catalysts include SAPO-34, SAPO-18, SAPO-5, and Beta. Advantages include reduced production of C1 hydrocarbons, C4 and higher hydrocarbons, or both; long catalyst lifetimes; desirable conversions; and desirable proportions of C2 and C3 paraffins.


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