The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 13, 2018

Filed:

Oct. 11, 2016
Applicant:

Novomer, Inc., Boston, MA (US);

Inventors:

Richard V. Porcelli, Ithaca, NY (US);

Jay J. Farmer, Ithaca, NY (US);

Robert E. Lapointe, Ithaca, NY (US);

Assignee:

Novomer, Inc., Boston, MA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 63/02 (2006.01); C07C 51/09 (2006.01); C07C 51/12 (2006.01); C07C 67/36 (2006.01); C08G 63/06 (2006.01); C08G 63/08 (2006.01); C07C 67/475 (2006.01); C07D 301/08 (2006.01); C07D 305/12 (2006.01); C08G 63/81 (2006.01); C08G 63/82 (2006.01); C07C 67/03 (2006.01);
U.S. Cl.
CPC ...
C07C 51/09 (2013.01); C07C 51/12 (2013.01); C07C 67/03 (2013.01); C07C 67/36 (2013.01); C07C 67/475 (2013.01); C07D 301/08 (2013.01); C07D 305/12 (2013.01); C08G 63/06 (2013.01); C08G 63/08 (2013.01); C08G 63/81 (2013.01); C08G 63/82 (2013.01); C08G 63/823 (2013.01); Y02P 20/125 (2015.11);
Abstract

In one aspect, the present invention encompasses integrated processes for the conversion of epoxides to acrylic acid derivatives and polyesters. In certain embodiments, the methods of the present invention comprise the steps of: providing a feedstock stream comprising an epoxide and carbon monoxide; contacting the feedstock stream with a metal carbonyl in a first reaction zone to effect conversion of at least a portion of the provided epoxide to a beta lactone; directing the effluent from the first reaction zone to a second reaction zone where the beta lactone is subjected to conditions that convert it to a compound selected from the group consisting of: an alpha beta unsaturated acid, an alpha beta unsaturated ester, an alpha beta unsaturated amide, and an optionally substituted polypropiolactone polymer; and isolating a final product comprising the alpha-beta unsaturated carboxylic acid, the alpha-beta unsaturated ester, the alpha-beta unsaturated amide or the polypropiolactone.


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