The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 13, 2018

Filed:

Dec. 19, 2014
Applicant:

Archer Daniels Midland Company, Decatur, IL (US);

Inventors:

Kenneth Stensrud, Decatur, IL (US);

Padmesh Venkitasubramanian, Forsyth, IL (US);

Assignee:

Archer Daniels Midland Company, Decatur, IL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 67/08 (2006.01); C07D 307/42 (2006.01); C07D 493/04 (2006.01); C07C 67/343 (2006.01); C07C 68/06 (2006.01); C07D 307/12 (2006.01);
U.S. Cl.
CPC ...
C07D 307/42 (2013.01); C07C 67/08 (2013.01); C07C 67/343 (2013.01); C07C 68/06 (2013.01); C07D 307/12 (2013.01); C07D 493/04 (2013.01);
Abstract

A method of preparing a glycol mono-ether or mono-acetate, or carbonate involving either one of two pathways from alkylene glycols, HMF or its reduction derivative products (i.e., FDM, bHMTHFs), is provided. In particular, according to one pathway, the alkylene glycol, HMF or FDM, bHMTHFs are reacted with a dialkyl carbonate in the presence of a deprotonating agent, in substantial absence of an extrinsic catalyst, to produce an ether, and subsequently reacting the ether with an acid base. According to the other pathway, alkylene glycols are reacted with an acetate donor in the presence of an acid, base, to generate an alkylene mono-acetate, and etherified with a carbonate in the presence of a deprotonating agent.


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