The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.
The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.
Patent No.:
Date of Patent:
Jan. 23, 2018
Filed:
Feb. 05, 2015
Process for the joint preparation of 1, 3, 3, 3-tetrafluoropropene and 2, 3, 3, 3-tetrafluoropropene
Xi'an Modern Chemistry Research Institute, Xi'an, Shaanxi, CN;
Jian Lv, Shaanxi, CN;
Hui Ma, Shaanxi, CN;
Bo Wang, Shaanxi, CN;
Wei Zhang, Shaanxi, CN;
Zhiqiang Yang, Shaanxi, CN;
Yujie Gu, Shaanxi, CN;
Wei Mao, Shaanxi, CN;
Jijun Zeng, Shaanxi, CN;
Xiaobo Tang, Shaanxi, CN;
Zhenhua Zhang, Shaanxi, CN;
Xi'an Modern Chemistry Research Institute, Xi'an, CN;
Abstract
A process for the joint preparation of 1,3,3,3-tetrafluoropropene and 2,3,3,3-tetrafluoropropene, comprising: (a) starting materials comprising at least one compound having the structure of formula I, II or III are reacted with hydrogen fluoride, producing 1,2,3-trichloro-3,3-difluoropropene, 1,2,3-trichloro-1,1,2-trifluoropropane, and 1,2,3-trichloro-1,1,3-trifluoropropane; in the compounds of said formulae CFCl═CCl—CHFCl(Formula I), CFClCHCl═CHCl (Formula II), and CFClCFClCHFCl(Formula III), m=0, 1, 2; n=1, 2; p=2, 3; x=1, 2, 3; y=1, 2; z=1, 2 and 4≦x+y+z≦6; (b) the 1,2,3-trichloro-3,3-difluoropropene, 1,2,3-trichloro-1,1,2-trifluoropropane and 1,2,3-trichloro-1,1,3-trifluoropropane undergo dechlorination, producing 3-chloro-3,3-difluoropropyne, 3-chloro-2,3,3-trifluoropropene and 3-chloro-1,3,3-trifluoropropene; and (c) the 3-chloro-3,3-difluoropropyne, 3-chloro-2,3,3-trifluoropropene and 3-chloro-1,3,3-trifluoropropene are reacted with hydrogen fluoride, simultaneously yielding 1,3,3,3-tetrafluoropropene and 2,3,3,3-tetrafluoropropen.