The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 16, 2018

Filed:

Mar. 09, 2015
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Todd E. Detjen, Houston, TX (US);

Robert G. Tinger, Friendswood, TX (US);

Gary D. Mohr, Sunset, SC (US);

David B. Looney, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 38/10 (2006.01); B01J 37/18 (2006.01); B01J 29/072 (2006.01); C07C 5/27 (2006.01); C07C 6/12 (2006.01); C07C 15/08 (2006.01); B01J 38/04 (2006.01); B01J 29/068 (2006.01);
U.S. Cl.
CPC ...
B01J 38/10 (2013.01); B01J 29/072 (2013.01); B01J 37/18 (2013.01); B01J 38/04 (2013.01); C07C 5/27 (2013.01); C07C 6/12 (2013.01); C07C 15/08 (2013.01); B01J 29/068 (2013.01); B01J 2229/186 (2013.01);
Abstract

A method of reducing the amount of carbon monoxide present during the metal reduction step of start-up, thus, maintaining metal dispersion and improving the metal reduction and catalyst yields. Carbon monoxide formation is minimized during the start-up procedure and during the initial catalyst dryout phase in a hydrogen-containing atmosphere, gas is purged from the reactor system, either continuously at constant pressure or by a series of pressure/depressure cycles, to remove carbon monoxide. The purging is conducted at temperatures of about 30-500° C. and pressures of about −90-5,000 kPa(g) (−0.9-50 bar(g)). In this temperature range, carbon monoxide absorbed to the surface of the metal will desorb into the hydrogen-containing atmosphere and can be removed from the system along with carbon monoxide present in the atmosphere through the purging.


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