The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 09, 2018

Filed:

Feb. 05, 2015
Applicant:

Xi'an Modern Chemistry Research Institute, Xi'an, Shaanxi, CN;

Inventors:

Jian Lv, Shaanxi, CN;

Hui Ma, Shaanxi, CN;

Jijun Zeng, Shaanxi, CN;

Wei Zhang, Shaanxi, CN;

Zhijun Hao, Shaanxi, CN;

Sheng Han, Shaanxi, CN;

Yongmei Du, Shaanxi, CN;

Jianping Kang, Shaanxi, CN;

Chunying Li, Shaanxi, CN;

Fengxian Li, Shaanxi, CN;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C07C 17/23 (2006.01); C07C 17/25 (2006.01); C07C 17/093 (2006.01); C07C 21/18 (2006.01); B01J 23/883 (2006.01); C07C 17/383 (2006.01); B01J 23/89 (2006.01); B01J 27/138 (2006.01); B01J 35/00 (2006.01); C07C 17/20 (2006.01); C07C 19/08 (2006.01);
U.S. Cl.
CPC ...
C07C 17/23 (2013.01); B01J 23/894 (2013.01); B01J 23/8906 (2013.01); B01J 23/8986 (2013.01); B01J 27/138 (2013.01); B01J 35/0006 (2013.01); C07C 17/206 (2013.01); C07C 17/25 (2013.01); C07C 17/383 (2013.01); C07C 19/08 (2013.01); C07C 21/18 (2013.01);
Abstract

Disclosed is a process for the preparation of 2,3,3,3-tetrafluoropropene, comprising the following two reaction steps: a. a compound having the formula CFClCFClCHCl undergoes gas-phase fluorination with hydrogen fluoride through n serially-connected reaction vessels in the presence of a compound catalyst, producing 2,3-dichloro-1,1,1,2-tetrafluoropropane, 1,2,3-trichloro-1,1,2-trifluoropropane, and 1,3-dichloro-1,1,2,2-tetrafluoropropane; in said formula, x=1, 2, 3, y=1, 2, and 3≦x+y≦5; b. the 2,3-dichloro-1,1,1,2-tetrafluoropropane, 1,2,3-trichloro-1,1,2-trifluoropropane, and 1,3-dichloro-1,1,2,2-tetrafluoropropane undergo gas-phase dehalogenation with hydrogen in the presence of a dehalogenation catalyst, producing 2,3,3,3-tetrafluoropropene and 3-chloro-2,3,3-trifluoropropene, then separation and refining are performed, producing 2,3,3,3-tetrafluoropropene. The present invention is primarily used to produce 2,3,3,3-tetrafluoropropene.


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