The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 09, 2018

Filed:

Jul. 25, 2012
Applicants:

Nikolai Nesterenko, Nivelles, BE;

Delphine Minoux, Nivelles, BE;

Cindy Adam, Wierde, BE;

Jean-pierre Dath, Beloeil, BE;

Joseph Lopez, Saint Julien les Rosiers, FR;

Patrick Euzen, Paris, FR;

Inventors:

Nikolai Nesterenko, Nivelles, BE;

Delphine Minoux, Nivelles, BE;

Cindy Adam, Wierde, BE;

Jean-Pierre Dath, Beloeil, BE;

Joseph Lopez, Saint Julien les Rosiers, FR;

Patrick Euzen, Paris, FR;

Assignees:

IFP ENERGIES NOUVELLES, Rueil Malmaison, FR;

TOTAL RESEARCH & TECHNOLOGY FELUY, Seneffe, BE;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 1/24 (2006.01); B01J 37/10 (2006.01); B01J 37/28 (2006.01); B01J 29/40 (2006.01); B01J 29/85 (2006.01);
U.S. Cl.
CPC ...
C07C 1/24 (2013.01); B01J 29/40 (2013.01); B01J 29/85 (2013.01); B01J 37/10 (2013.01); B01J 37/28 (2013.01); C07C 2527/14 (2013.01); C07C 2529/06 (2013.01); C07C 2529/40 (2013.01); Y02P 20/52 (2015.11); Y02P 30/42 (2015.11);
Abstract

A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.


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