The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 02, 2018

Filed:

Dec. 12, 2014
Applicant:

Archer Daniels Midland Company, Decatur, IL (US);

Inventors:

Kenneth Stensrud, Decatur, IL (US);

Alexandra Sanborn, Lincoln, IL (US);

Stephen Howard, Sherman, IL (US);

Erik Hagberg, Decatur, IL (US);

Assignee:

Archer-Daniels Midland Company, Decatur, IL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 29/76 (2006.01); C07D 493/04 (2006.01); B01J 27/053 (2006.01); B01J 27/16 (2006.01); B01J 31/02 (2006.01); C07C 29/154 (2006.01); B01D 1/22 (2006.01); B01D 3/10 (2006.01); B01D 15/18 (2006.01); B01D 15/36 (2006.01);
U.S. Cl.
CPC ...
C07C 29/76 (2013.01); B01D 1/22 (2013.01); B01D 3/10 (2013.01); B01D 15/1821 (2013.01); B01D 15/361 (2013.01); B01J 27/053 (2013.01); B01J 27/16 (2013.01); B01J 31/0225 (2013.01); B01J 31/0227 (2013.01); C07C 29/154 (2013.01); C07D 493/04 (2013.01); B01J 2231/4288 (2013.01); B01J 2531/002 (2013.01); B01J 2531/007 (2013.01);
Abstract

A process for preparing cyclic dehydration products from sugar alcohols is described. The process involve using a mixed-acid catalyst reaction mixture containing a reducing acid, having a pKa of about 1.0-1.5, and at least a strong Brønsted acid or a Lewis acid, having a pKa≦0, or both acids in a solution to dehydrate and ring close said sugar alcohol. Synergistically, the mixed-acid catalysis can produce greater amounts of the desired product at similar levels of compositional accountability than either of the component acid catalysts acting alone.


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